Thermo Fisher Scientific Orion 2111XP Sodium Analyzer User guide

User Manual



Thermo Scientific

Orion 2111XP

Sodium Analyzer

UM-263639-005 • Revision B • January 2017

property of Thermo Fisher Scientific Inc. and its subsidiaries. Specifications, terms and

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consult your local sales representative for details.

No part of this publication may be reproduced, transmitted, transcribed, stored in a

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form or by any third party, without the prior written permission of Thermo Fisher

Scientific.

Disclaimer

Thermo Fisher Scientific does not accept any responsibility for any damage caused to its

products by unauthorized personnel. Use of non-Thermo Scientific™ reagents and/or

replacement parts will void all warranties.

Contents

Section 1 General Information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Features and Benefits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Application Packages . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Principles of Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Principles of Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Double Known Addition (DKA) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Offline Calibration. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Fluidics Diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Two Channel Analyzer Configurations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Section 2 Analyzer Preparation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10

Unpacking the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Mounting and Plumbing Instructions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Sample Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Electrical Wiring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Safety Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

Warning Labels and Locations. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Wiring the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Terminal Assignments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15

Electrode Wiring Assignments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

Installation of DIPA Reagent and Diffusion Tubing . . . . . . . . . . . . . . . . . . . . . . . . . 17

Installation of Ammonia Reagent and Diffusion Tubing . . . . . . . . . . . . . . . . . . . . . . 20

Installation of New Electrode Cables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Installation of the ATC Probe . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Installation of a New Reference Electrode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Section 3 Analyzer Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24

Description of Basic Controls . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

Description of Keypad Icons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

Use of the Setup Mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

Setup Mode Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

Shutdown and Start-Up Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

Section 4 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .55

Calibration Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55

Flow Cell Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56

Rinsing the Flow Cell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

Air Regulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

Before Performing a DKA Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58

Performing a DKA Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60

Calibration Abort Steps . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .62

Calibration Error Codes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .63

Calibration At Custom Concentrations Using DKA . . . . . . . . . . . . . . . . . . . . . . . . . .64

Span Check Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .65

Offline Calibration Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .65

Section 5 Analyzer Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

Maintenance Schedule . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .67

Weekly Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .67

Monthly Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .68

Yearly Preventive Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .72

Section 6 Troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75

Diagnostics Mode . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .75

Slope Problems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .80

Troubleshooting Matrix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .82

Error/Event Codes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .83

Resetting the Analyzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .86

Serial Number and Software Revision . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .87

Service and Repair . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .87

Section 7 Customer Service . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

Notice of Compliance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .90

Statement of Conformity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .91

WEEE Compliance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .92

Terms and Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .92

Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .95

Mounting Dimensions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .95

ISE Default Values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .96

Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .96

Ordering Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .100

Accessory Options . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .102

Field Replaceable Parts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .102

Recommended Consumables for Annual Operation . . . . . . . . . . . . . . . . . . . . . . . .103

Pipet Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .104

Pipet Techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .105

Thermo Scientific Orion 2111XP Sodium Analyzer | 1

S E C T I O N

1General Information

This user guide covers the operation, maintenance and troubleshooting for the Thermo

Scientific Orion 2111XP sodium analyzer, which offers unmatched reliability in monitoring

critical sample streams throughout the power/steam generation and industrial water industry.

Introduction

Monitoring the sodium ion content of steam and water circuits to produce accurate and

reproducible results requires a very well designed and maintained system. The system must

optimize the fluidic design with the sensing technology to enable low level (ppb) measurement

of the contaminants as well as measuring across the linear range of the analyzer.

The 2111XP sodium analyzer meets all of the criteria for accurate and dependable sodium

monitoring and more. The 2111XP analyzer incorporates innovative technologies that include:

 Premium electrodes

 Accurate and precise flow cell design

 Marquee help screen

 Pump-less reagent addition and DKA calibration system

1 | General Information

2 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Thermo Scientific Orion 2111XP Sodium Analyzer

Markets

 Power

 Semiconductor

 Chemical and petrochemical

 Pulp and paper

Applications

 Feedwater / make-up water

 Boiler feedwater

 Drum boilers

 Demineralized water

 Steam condensate

 Cation exchange breakthrough

 High acid samples

Features and Benefits

The Thermo Scientific Orion 2111XP sodium analyzer features an expandable platform design

that incorporates over 30 years of expertise in sodium measurements combined with innovative

Thermo Scientific Orion technologies for superior performance.

 Choice of application/reagent packages:

Flexible configurations for applications ranging from low-level detection to high acid

samples.

 Accurate and precise measurements in the range of 0.30 ppb to 200 ppm:

Reliable measurements and a wide measurement range with selectable resolution.

 Premium reference and sensing electrodes:

Superior accuracy and stability over a wide temperature range.

 Advanced flow cell design with air stirring:

Automatic sample handling and contamination control with no moving parts.

 Patented scrolling marquee:

Intuitive menu-driven, digital user interface.

 Data log of previous measurements and calibration:

View measurement, calibration and error history.

 Self diagnostics:

Ease of maintainability.

 Password protection:

Security and peace of mind for your operation.

 Auto-ranging electronics with an easy to read backlit LCD display:

Analyzer determines the best range.

1 | General Information

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 3

Application Packages

The Thermo Scientific Orion 2111XP sodium analyzer is ideally suited to meet the demanding

needs of high purity water measurements and high acid-cation exchange applications, all in one

system and all from one of the most trusted names in sodium monitoring.

The 2111XP analyzer is offered in three application packages that are uniquely designed to

accommodate the changing requirements for successful sodium monitoring. Our flexible reagent

kits are available in prepackaged bottles for safe and convenient replacement – save your

valuable time and money!

 Ammonia Application Package – for general purpose sodium measurements, provides up

to 60 days of continuous operation.

 Diisopropylamine (DIPA) Application Package – for low range sodium detection,

provides up to 60 days of continuous operation.

 Cation/High Acid Application Package – for cation exchange breakthrough and high acid

samples, provides up to 45 days of continuous operation.

Application Packages

Ammonia Application Package

(Cat. No. 2111XA)

Reagent: Ammonia

Range: 0.30 ppb to 200 ppm

Accuracy: ± 5% or 0.3 ppb (with DKA calibration)

DIPA Application

Package

(Cat. No. 2111XD)

Reagent:

Diisopropylamine (DIPA)

Range: 0.10 ppb to 10 ppm

Accuracy: ± 5% or 0.1 ppb (with DKA calibration)

Cation / High Acid

Application Package

(Cat. No. 2111XC)

Reagent:

Ammonia

Range: 1.0 ppb to 200 ppm

Accuracy: ± 5% or 2 ppb (with DKA calibration)

1 | General Information

4 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Principles of Operation

The sample enters the Thermo Scientific Orion 2111XP sodium analyzer and passes through

the inlet valve, bypass/needle valve, inlet filter, pressure regulator, flow meter and into the

restrictor tubing. The sample then passes through the flow cell manifold into a reagent bottle and

through a diffusion tubing assembly where pH adjustment takes place. The pH-adjusted sample

then flows back through the manifold into the flow cell as air is introduced from the air pump to

ensure proper mixing and fast response. The sample then flows into an atmospheric drain via

the diverter valve.

Figure 1: 2111XP Schematic

The sensing electrode responds logarithmically to changes in the sodium ion concentration. This

response is described by the Nernst equation:

E = E0 + 2.3 (RT/nF) log (C/Ciso)

Where:

E = measured electrode potential, mV

E0= potential, when C equals Ciso, mV

Safety Drain for

Reagent Overflow

Restrictor Tubing

Pressurizes Flow Cell

Calibration Mode - PUSH

to Initiate Siphoning

Valve Positions

Sample/Measure Mode - PULL

Analyzer

12345

Power

4-20mA Output

Air Pump

FFllooww MMeetteerr

Bypass / Needle

Inlet Valve

Valve and Filter

Regulator

Valve

Reference Solution

Port

Calibration

REF

TEMP

Sense

Flow Cell Block

Calibration Level

Air Filter

Reagent

Reagent Bottle

Diffusion Tube

Fluid Path

Reagent Manifold

Electric

Fluid Restrictor Tubing

Air Path

Reference Solution Path

Diffusion Tubing

KEY

Reagent Overflow Path

Main Feed

Air Inlet

Measure Level

Drain

Check

Valve

Sample

VVVaaaalllvlvveee

Cal

1 | General Information

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 5

R = ideal gas constant

T = temperature of sample, degrees K

n = valence of ionic species (+1 for sodium ion)

F = Faraday’s constant

C = effective sodium ion concentration (activity)

Ciso = concentration (activity) of sodium ion where potential E is temperature

independent (isopotential point)

The above equation indicates that the measured potential varies with both temperature and the

concentration of the ion of the interest. In order to eliminate error caused by fluctuations in

sample temperature, the 2111XP microprocessor constantly updates temperature corrections

from data supplied by the ATC probe.

From the Nernst equation, the theoretical response of a sodium ion selective electrode to a

ten-fold change in concentration at 25 °C is 59.16 mV. This is referred to as the electrode slope

(S). Most electrodes, however, do not exhibit a theoretical slope. Therefore, the analyzer is

calibrated to determine its actual value. Two standards are used to provide information

necessary for the microprocessor to compute the actual slope and E0 for use during sample

analysis.

In order to eliminate interference from hydrogen ions, which can become significant when

measuring low levels of sodium, the 2111XP analyzer raises the sample pH. This pH adjustment

is accomplished by the patented passive-diffusion process wherein the sample passes through

a length of tubing contained in the reagent bottle. The reagent diffuses through the tube wall and

mixes with the sample, which raises the sample pH.

Principles of Calibration

Calibration procedures for analytical instruments are important and must be performed carefully.

The calibration procedure used in the Thermo Scientific Orion 2111XP analyzer is a variation of

Double Known Addition (DKA) using advanced electrode and flow cell technology in

combination with the passive diffusion system. This method has the distinct advantages of being

fast, easy, and accurate.

Double Known Addition (DKA)

Before calibration begins, the diverter valve is pushed in to divert flow from the measure drain,

allowing the flow cell to fill.

At the beginning of the DKA calibration the actual concentration in the sample is unknown. The

analyzer measures the potential (Es) and stores this value in the microprocessor. A known

amount of standard 1 solution is added to the flow cell, which increases the concentration (Cs)

with a corresponding known amount (dc1). During this process, air is pumped into the flow cell,

1 | General Information

6 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

thoroughly mixing sample and standard in a closed- loop system. The new potential (E1) is

measured and stored automatically when stability is reached. Adding standard 2, preferably 10

times more concentrated than standard 1, increases the concentration (dc2) in the sample

reservoir. Again, the new potential (E2) is measured and stored when the reading is stable. Now,

we have the following three unknowns:

Es = E0 + S(Ts/298.15) log (Cs/Ciso)

E1 =E

0 + S(T1/298.15) log [(Cs + dC1)/Ciso]

E2 =E

0 + S(T2/298.15) log [(Cs+ dC1+ dC2)/Ciso]

S is the Slope at 25 °C (298.15 K)

T is the temperature in Kelvin, measured when the potential E is measured.

Es, E1, E2 have been determined during the calibration procedure. The microprocessor solves

these three equations, to obtain the values of S and E0. The calibration result is stored for use

during online monitoring to convert the measured potential and temperature in the sample into

concentration values in either ppm or ppb.

When the calibration is complete the flow cell drains as the sample flow returns. The flow cell

volume returns to the measurement level. After allowing approximately 30 minutes for

concentrated calibration solution to be flushed from the system, the 2111XP analyzer can begin

sample measurement again.

In addition to Double Known Addition (DKA), the 2111XP analyzer also allows the operator the

ability to perform an offline calibration.

Figure 2: Flow Cell Volume for DKA

1 | General Information

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 7

Offline Calibration

The offline calibration feature of the 2111XP analyzer allows the operator to adjust the analyzer

to values determined by alternate methods used in their laboratory such as elemental

spectroscopy and ion chromatography.

The offline calibration is essentially a one point calibration. To perform an offline calibration, a

sample is taken from the bypass of the analyzer; the sample concentration value is stored in

memory; the sample is analyzed by an alternate method of choice; the previously stored reading

is adjusted to the lab method result; and the analyzer is then returned to the analysis mode. The

term “offline calibration” refers only to the fact that a sample from 2111XP analyzer bypass is

taken “offline” for laboratory analysis; in fact, no downtime is experienced during the procedure

and the analyzer remains online throughout.

Fluidics Diagram

Figure 3: Fluidics Diagram

Scrolling Marquee

LCD Display

Warning Icon

Mode Indicator

Mounting

Hole

Keypad

Flow Cell

Reservoir

Siphon Tube

Flow Cell Block

Inlet Valve

Reagent

Bottle

Adapter

Assembly

Pressure

Regulator

Status Indicators

Flow Meter

Calibration Port

Reference

Filling

Solution

Restructor

Tube

Assembly

Air Pump

Bypass/Needle

Valve

Inlet Filter

Reagent

Manifold

Diverter Valve

Diffusion Tubing

Assembly

Reagent Bottle

1 | General Information

8 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Glossary

Refer to Figure 3.

Inlet Valve – Accepts the sample stream via 1/4 inch NPTF connector. The operator must

supply the sample with a pressure between 8 and 100 psig.

Inlet Filter – 60 micron stainless steel filter traps particulate matter in the sample stream.

Bypass/Needle Valve – Used to redirect flow in the bypass system.

Pressure Regulator – Adjusts flow on the incoming sample stream.

Flow Meter – Measures sample flow rate.

Restrictor Tube Assembly – Used in conjunction with the pressure regulator to lower

downstream pressure.

Reagent Manifold – Directs sample flow in and out of the reagent bottle assembly.

Reagent Bottle Adapter Assembly – Connects the reagent bottle assembly to the manifold.

Diffusion Tubing Assembly – Semi-permeable tubing through which reagent diffuses into the

sample.

Reagent Bottle – Contains water-soluble amine or ammonia reagent that raise the sample pH.

Flow Cell – Contains sodium sensing electrode, reference electrode and ATC probe.

Diverter Valve – Allows the flow cell reservoir to fill during calibration by forming a closed-loop

system.

Sodium Sensing Electrode – Senses sodium ions in sample stream and produce an electrical

potential dependent on sample concentration.

Reference Electrode – Provides a constant reference potential and completes the

measurement circuit.

Reference Electrode Filling Solution Bottle – Provides constant flow of electrolyte solution

through reference electrode for maximum stability.

ATC Probe – Measures sample temperature and inputs data to microprocessor for automatic

temperature compensation (ATC).

1 | General Information

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 9

Calibration Port – Allows introduction of standards to the sample reservoir during calibration.

LCD Display – Provides digital readouts of concentration, temperature, millivolts and error

codes.

Air Pump – Used to mix the sample during both measurement and calibration.

Keypad – Consists of five mode keys, four prompt indicator lights, two scroll keys and one key

for entering data. Mode and error indicators are also incorporated on the keypad.

Status Indicator – Two LED lights that illuminate according to current status of the analyzer.

Note: When either the yellow or red LED is lit, there may be an entry in the diagnostics mode

that indicates the error. The logging feature must be initiated in the setup mode. Refer to

Section 3, Use of the Setup Mode for instructions.

Two Channel Analyzer Configurations

A pH/ORP module or conductivity module can be added by the operator to the second channel

of the Thermo Scientific Orion 2111XP sodium analyzer for the ultimate flexibility in

measurement capabilities. The 2100 series pH/ORP and conductivity analyzers provide

accurate and reliable measurements in ultra pure water as well as the harshest industrial

environments. Combined with decades of superior Thermo Scientific Orion sensor technology,

our systems provide rapid results with complete stability.

When a pH/ORP module or conductivity module is installed on the second channel of the

2111XP sodium analyzer, refer to the Thermo Scientific Orion 2100 Series pH/ORP Analyzer

and Conductivity Analyzer User Guide for detailed instructions on operating the pH/ORP or

conductivity analyzer. Visit www.thermofisher.com/water to download any of the 2100 series

analyzer user guides.

Green Light: Indicates that system is in correct working condition.

Yellow Light: Indicates a warning, system in hold or that maintenance is required.

Red Light: Indicates that something is seriously wrong.

Cat.No Description

2100PH2 Second channel module for pH/ORP

2100CD2 Second channel module for conductivity

10 | Orion 2111XP Sodium Analyzer Thermo Scientific

S E C T I O N

2Analyzer Preparation

WARNING: The instructions provided in this user guide are recommendations from the

manufacturer to ensure safe and correct operation of the analyzer. If the analyzer is not used as

recommended by the manufacturer this can lead to incorrect operation or injury.

Unpacking the Analyzer

Thermo Scientific Orion analyzers are assembled, tested and packaged with great care. Refer

to Figure 4.

Report any obvious damage of shipping container to carrier and hold for inspection. The carrier

(not Thermo Fisher Scientific) is responsible for any damage incurred during shipment.

1. Open the outer box. Remove the top two foam corner support pieces.

2. Open the inner box. This box should contain the analyzer and ATC temperature probe,

sodium electrode box, reference electrode box, low level standards kit (two 2 oz. bottles of

standard 1, 19.1 ppm sodium; two 2 oz. bottles of standard 2, 192 ppm sodium; and

one 2 oz. bottle of etching solution), high level standards kit (two 2 oz. bottles of standard

1, 1910 ppm sodium; two 2 oz. bottles of standard 2, 19200 ppm sodium; and one 2 oz.

bottle of etching solution), the options kit and user guide CD.

3. Remove the cardboard retaining shell by sliding it over the entire mounting board and the

analyzer.

4. Carefully remove the entire mounting board with analyzer from the inner box.

Note: Do not lift or pull the analyzer by the fluidics or the electronic components. Use the

back panel to lift the analyzer system.

2 | Analyzer Preparation

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 11

Figure 4: Unpacking the Analyzer

5. Unbolt the analyzer from the mounting board by removing the four mounting bolts with a

9/16'' wrench. These bolts may be discarded.

6. Carefully place the analyzer at a convenient location until proper installation can be

completed.

Mounting and Plumbing Instructions

Refer to the Appendix, Mounting Dimensions section.

WARNING: Do not connect power prior to the mounting and plumbing of the analyzer.

Recommendations

 Select a site for the analyzer that allows it to be permanently bolted with ample height for

atmospheric drain operation. Be sure that there is ready access to the electronic controls,

calibration port and electrodes.

 A clearance of 15 inch (about 40 cm) must be allowed above the flow cell calibration port.

Insert the pipet vertically (not angled) during the calibration.

 The analyzer location must permit connections to a sample line, drain and AC power supply

and any connections for output devices.

 The analyzer should be mounted as close to the sampling point as possible. This ensures

the fastest possible response to a changing sample condition. Refer to the Appendix,

Sample Conditions section.

 For proper flow cell operation, the analyzer must be installed straight and level upon its

mounting location. Failure to level the analyzer may cause poor siphoning in the flow cell.

2 | Analyzer Preparation

12 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Instructions

1. Prepare the mounting holes. Carefully lift the analyzer and bolt it into place. Do not lift the

analyzer by holding on to any of the plumbing or fluid handling components.

2. Connect a waste line to the outlet of the analyzer, which is 3⁄4'' NPT male. The waste line

should be connected to a drain of sufficient capacity, 0.5 inch (1.27 cm) OD is

recommended.

3. Connect a sample line to the inlet of the analyzer, which is 1⁄4'' NPT female. It is

recommended that a shutoff valve be installed at the sampling point.

4. The analyzer must be mounted and leveled vertically for proper operation.

Sample Requirements

Additional information is listed in the Appendix, Specifications section.

Sample inlet connection – 1/4'' NPTF. If particulate matter is present in the sample,

pre-filtration is necessary. The 60 micron stainless steel filter located after inlet valve will remove

moderate amounts of particulates.

Flow rate – 40 mL/minute (nominal) for the Ammonia and DIPA Application Packages and 25

mL/minute (nominal) for the Cation/High Acid Application Package.

Pressure – 8 to 100 psig. Consult Technical Support for details on sample handling if the

pressure is outside of this range.

Temperature – Temperature must be between 5 and 45°C.

Sodium level – Sodium levels are read directly in ppb or ppm, when calibrated with Thermo

Scientific Orion sodium standards 1 and 2.

Sample alkalinity – Sample alkalinity should be less than 250 ppm CaCO3 equivalent. For

higher sample alkalinity, contact Technical Support.

Electrical Wiring

The warning icon highlights important information that should be strictly followed when using the

analyzer for your own safety. Failure to follow these instructions may result in injuries.

WARNING: Read and observe the following safety recommendations.

Safety Requirements

 Prior to wiring, a switch or circuit breaker for disconnecting the analyzer from power supply

should be installed.

The switch should be in close proximity to the analyzer and with easy reach of the user.

The switch should be marked as the disconnecting device for the analyzer.

2 | Analyzer Preparation

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 13

 To reduce the risk of shock hazard, disconnect the power prior to opening the analyzer.

 Before connecting the analyzer to the main, make sure that the voltage lies within either

range: 100-120V 200mA / 200-240V 100mA; 50-60 Hz AC.

 Cutting off the power by disconnecting power source will not reset the analyzer. This

analyzer incorporates a non-volatile memory and will maintain calibration and settings after

power failure. Battery power is supplied to the display for the date and time functions.

 If a repair is required, or to arrange Return Material Authorization, call Technical Support or

contact your local authorized dealer.

 Installation and wiring of the analyzer may only be carried out in accordance with applicable

local and national codes per this user guide.

 Be sure to observe the technical specifications and input ratings.

Warning Labels and Locations

WARNING: The following section provides important information that should be strictly followed

when using the analyzer for your own safety. Failure to follow these instructions may result in

injuries.

The safety warning icons are used in two locations on the analyzer.

 Faceplate – Refer to Figure 5.

Figure 5: Faceplate

 Power supply – Refer to Figure 6.

Figure 6: Power Supply

.

Note: Replace the fuse only with a fuse of same rating.

Ch 1 status Ch 2 status

t Ch 1

t Ch 2

2 | Analyzer Preparation

14 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Wiring the Analyzer

WARNING: Read and observe the following requirements. If you install the wrong fuse for your

system, you could damage the analyzer. Make sure that you select the correct fuse rating and

discard the additional fuses supplied in the fuse kit.

Required Tools

 Options kit – includes fuses, cable glands, conduit fitting and green screw terminal.

 Phillips head screwdriver.

 2 mm blade flat-head screwdriver.

Figure 7: Electronic Enclosure with Cable

Glands

1. Open the faceplate – loosen the four screws using a Phillips head screwdriver. The

electronics faceplate will open via the hinge pin connection.

2. Remove one or two of the two unused cable glands as required for wiring power cable or

auxiliary connections. Power cable optional hole locations are shown in Figure 7.

3. Select and install the appropriate size cable gland or conduit fitting as required.

Figure 8: Terminal Connector Location

Terminal Connector

2 | Analyzer Preparation

Section

Thermo Scientific Orion 2111XP Sodium Analyzer | 15

4. Feed the power cable through the conduit or cable glands as required.

5. Wire the power cable to the green screw terminal connector from the options kit. Select

correct terminal for hot conductor depending on line voltage, insert ground wire into the

correct terminal and connect the other cable to the neutral terminal. Refer to Figure 8 for

terminal connector location.

6. Plug the terminal connector into the power supply. Refer to Figure 6.

7. The universal power supply uses both fuses in the fuse kit. Install by inserting the fuse in the

fuse holder and secure it using the twist and lock method. The fuses are clearly labeled with

the appropriate voltages for your system. Refer to Figure 6 and Figure 8 for the correct fuse

holder positions. Refer to the table below for fuses required.

Terminal Assignments

AC Voltage Fuse rating

115V 200mA, 250V, Fast Acting

230V 100mA, 250V Fast Acting

Terminal Layout Terminal Layout Terminal Layout Terminal Layout

1 mA1 output 9Relay 1 26 Sensing electrode 28 Do not connect

2GND common ground 10 Relay 1 27 Do not connect 29 Do not connect

3 mA2 output 11 Relay 2 30 Preamp power

4Air pump (ISE only) 12 Relay 2 31 Preamp ground

5Air pump (ISE only) 13 Relay 3 32 Shield

6Shield ground for conductivity 14 Relay 3 33 Shield

7Do not connect 15 Do not connect 34 Jumper to pin 26 when

using preamp

8Do not connect 16 Temperature ground

17 Temperature drive

18 Temperature sense

19 Solution ground

20 Conductivity drive +

21 Conductivity sense +

22 Conductivity sense -

23 Conductivity drive -

24 Reference electrode

25 Jumper to pin 24

when using preamp

2 | Analyzer Preparation

16 | Orion 2111XP Sodium Analyzer Thermo Scientific

Section

Figure 9: Terminal Assignments

Electrode Wiring Assignments

Sodium Electrode

26 Sensing Electrode Connect clear wire

33 Shield Connect black wire

Reference Electrode

24 Reference electrode Connect clear wire

32 Shield Connect black wire

2100TP Temperature Probe

16 Temperature ground /thermistor Connect white wire

17 Temperature drive /thermistor Connect green wire

19 Solution ground Connect red wire

2001TM Temperature Probe

16 Temperature ground /thermistor Connect white wire

17 Temperature drive /thermistor Connect green wire, jumper 17 and 18

18 Temperature sense Jumper to 17

19 Solution ground Connect red wire

2001SC pH Electrode

24 Reference electrode Connect black wire

26 Sensing electrode Connect clear wire

110250 ORP Electrode

19 Solution ground Connect black wire

24 Reference electrode Connect purple wire

26 Sensing electrode Connect coax center wire

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