ALTAIR
®
5X PID
12
PID Theory and Definitions
US
background ionization current.When only measuring concentration changes relative to a reference
ambient environment, fresh air can be used as the zero gas. When background hydrocarbon vapors
are present, MSA recommends using zero gas air.
Span Gas
Span gas is a reference gas used during calibration to determine the slope (response per unit concen-
tration) of the calibrated response curve.
For the 0-2000 ppm PID sensor the only allowable calibration gas is 100 ppm isobutylene.
See Chapter 4.10 "Calibration" for calibration instructions.
Response Factors
When a compound is ionized by photoionization, the ionized molecules are collected and converted to
a current. This response is a characteristic property of the specific compound which is influenced by
its molecular structure. The slope of the response curve (defined in picoamperes per ppm) is different
for different chemicals. To properly report the concentration for a given sample gas, the ALTAIR 5X PID
uses response factors. See Chapter 10 "PID Response Factor Table", for instructions on using the pre-
programmed list of response factors.
WARNING!
It is very important to have an understanding of PID basics when changing PID settings. Failure to
properly identify the VOC gas being measured and/or failures to select the correct Response Factor
alarm values (exposure, STEL, TWA) that match the desired Response Factor and/or the correct lamp
will result in erroneous readings or erroneous alarm limits that could cause death or serious personal
injury.
The response factor is defined as the ratio of the detector response for isobutylene to the detector
response for the sample gas. Response factors for a wide range of substances have been determined
experimentally. These response factors are programmed into the device. Note that the calibrated
response curve, and all programmed response factors are relative to isobutylene. Isobutylene has a
response factor of one.
The response factor is a multiplier that compensates for the difference between the response of the
sample gas and the response of isobutylene at 100ppm. Whenever the device detects the presence
of a VOC, it uses the response factor for the user-assigned target gas to convert the signal to the
correct, concentration. This is done by multiplying the equivalent isobutylene response by the response
factor for the set sample gas. The isobutylene response curve is calculated at every calibration.
If the response factor is known, a device calibrated with isobutylene can be used to calculate the actual
concentration of a target gas.
Calculating a Response Factor
To determine a response factor for a target chemical, perform the following simple procedure:
(1) Calibrate the ALTAIR 5X PID using isobutylene as the span gas.
(2) On the device, set the sample gas name to isobutylene.
(3) Apply a known concentration of the target chemical to the device and note the concentration
reported in the display.
The response factor for the target chemical relative to isobutylene:
RF target gas =
Actual known concentration
Concentration reported by device