Milwaukee M12 User manual

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Lithium‐ionBattery‐Rechargeable

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SECTION1:PRODUCTANDCOMPANYIDENTIFICATION



ProductName:Lithium‐ionBatteries‐RechargeableDrawingNumber:58‐97‐0500 

 IssueDate:January2020 

SupersedesDate:January2019



MilwaukeeElectricToolCorporationCompanyPhoneNumber:1‐262‐781‐3600or

13135WestLisbonRoad 1‐800‐729‐3878

Brookfield,WisconsinUSA53005‐2550EmergencyContactNumber:1‐800‐424‐9300

www.milwaukeetool.com Chemtrec:UnitedStatesonly

ForInternational:+1‐703‐741‐5970



SECTION2:HAZARDSIDENTIFICATION



HealthEnvironmentalPhysical

EyeIrritation:NoclassifiedhazardsAcuteToxicity:NoclassifiedhazardsFlammableliquid:Noclassifiedhazards

SkinIrritation:NoclassifiedhazardsChronicToxicity:Noclassifiedhazards

AcuteToxicity,Oral:Noclassified

hazards



AcuteToxicity,Inhalation:Noclassified

hazards





GHSLabel

Noapplicablelabeling 



HazardStatementsPrecautionaryStatements

Noexposureduringroutinehandlingofproduct



CLASSIFIEDHAZARDS

ThismaterialisnothazardousunderthecriteriaoftheFederalOSHAHazardCommunicationStandard29CFR1910.1200.This

SDScontainsvaluableinformationforthesafehandlingandproperuseofthisproduct.SavethisSDSforfuturereference.



OTHERHAZARDS

Flammable:

Organiccomponentswillburnifcellisincinerated.CombustionofcellcontentsmaycauseevolutionofHydrogenFluoride.



PotentialHealthEffects:

Fluorideinterfereswithnerveimpulseconductioncausingseverepainorabsenceofsensations



WARNING:

Noexposureduringroutinehandlingofproduct.HydrofluoricAcidexposureduringfirefighting:Thisinformationisgiven

fortheuseofprofessionalfirefightersrespondingtoawarehousefirewherefirefromothermaterialsmayincinerate

batteries.Thissectionisprovidedsolelyincaseofexposure,duringfirefighting,tothecombustionby‐products.



ProductInformationSheet

MaybeusedtocomplywithOSHA’sHazardCommunication

Standard29CFR1910.1200.

Thisstandardmustbeconsultedforspecificrequirements.

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Lithium‐ionBattery‐Rechargeable

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SECTION3:COMPOSITION/INFORMATIONOFINGREDIENTS



ChemicalNameCAS#Concentration

AluminumFoil 7429‐90‐50.1‐10

Biphenyl(BP)92‐52‐40.1‐0.3

CopperFoil7440‐50‐8 0.1‐10

Linear&CyclicCarbonatesolventsConfidential0‐17

GraphitePowder/Carbon7440‐44‐010‐30

MetalOxideorotherElectrolyte(proprietary)Confidential10‐50

LithiumHexaflurophosphate(LiPF6)21324‐40‐30‐5

PolyvinylideneFlouride(PVDF)24937‐79‐90.1‐5

StyreneButadieneRubber(SBR)Confidential<5

Aluminum,Steel,Nickelandotherinertmaterials ConfidentialRemainder



SECTION4:FIRSTAIDMEASURES



Noexposureduringroutinehandlingofproduct.Riskofexposureoccursonlyifthebatteryismechanicallyorelectricallyabused.



Noeffectunderroutinehandlingandusetoeyes,skinorifinhaled.Ingestionisnotlikely,giventhephysicalsizeandstateofthe

cell.Ifswallowed,seekmedicalattentionimmediately.



Ifexposuretointernalmaterialswithincellduetodamagedoutercasingthefollowingactionsarerecommended:



EYECONTACT:

Flushwithwaterfor15minuteswithoutrubbingandimmediatelyseekmedicalattention.



SKINCONTACT:

Washareaimmediatelywithsoapandwater.Ifirritationcontinuesseemedicalattention.



INHALATION:

Leaveareaimmediatelyandmovetofreshairandseekmedicalattention.



INGESTION:

Ifswallowed,contactPOISONCONTROLCENTERimmediately.



SECTION5:FIREFIGHTINGMEASURES



NFPA704HazardClassHMIS

   



SUITABLEEXTINGUISHINGMEDIA:

Waterspray,carbondioxide,drychemicalpowderorappropriatefoam.Useagentappropriateforsurroundingmaterials.



UNSUITABLEEXTINGUISHINGMEDIA:

None.



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Lithium‐ionBattery‐Rechargeable

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PRODUCTSOFCOMBUSTION:

Organiccomponentswillburnifincinerated.CombustionofcellcontentsmaycauseevolutionofHydrogenFluoride.Incaseof

fireinanadjacentarea,usewater,CO2,ordrychemicalextinguishersifcellsarepackedintheiroriginalcontainerssincethe

fuelofthefireisbasicallypaperproducts.



PROTECTIONOFFIREFIGHTERS:

HydrofluoricAcidexposureduringfirefighting:Thisinformationisgivenfortheuseofprofessionalfirefightersrespondingtoa

warehousefirewherefirefromothermaterialsmayincineratebatteries.Thissectionisprovidedsolelyincaseofexposure,

duringfirefighting,tothecombustionby‐products.



SECTION6:ACCIDENTALRELEASEMEASURES



PERSONALPRECAUTIONS:

Usestandardindustrialclothinginnormaluse.Ifhandlinglargecontainersofcellswearsteel‐toedfootwear.



ENVIRONMENTALPRECAUTIONS:

Nospecialprecautionsnecessary.



METHODSFORCONTAINMENT:

Transportcontaineroutdoors.Holdburnedcellsandfirecleanupsolidsfordisposalaspotentialhazardouswaste.Unburned

cellsarenothazardouswaste.Afirewithover100kgofcellsburntwilllikelyrequirereportingtoenvironmentalofficials.

Alwaysconsultandobeyallinternational,federalandlocalenvironmentallaws.



METHODSFORCLEAN‐UP:

Nodataavailable



OTHERINFORMATION:

Nodataavailable



SECTION7:HANDLINGANDSTORAGE



HANDLING:

Useonlyapprovedchargingequipment.Donotdisassemblebatteryorbatterypack.Donotpuncture,crushordisposeofinfire.



STORAGE:

Storeinacool,dryplaceawayfromsparksandflame.Keepbelow125°C.Keepabove‐60°C.Chargebetween0°Cand45°C.



SECTION8:EXPOSURECONTROLS/PERSONALPROTECTION



ChemicalNameOSHA

PEL

ACGIH

TLV

CaliforniaProp65

Reg.Y/N

IARC/NTP

Y/N

AluminumFoil TWA

5mg/m3*

TWA

5mg/m3*

NN

Biphenyl(BP)NANANN

CopperFoilNANANN

Linear&CyclicCarbonatesolventsNANANN

GraphitePowder/CarbonNANANN

MetalOxideorotherElectrolyte(proprietary)NANANN

LithiumHexaflurophosphate(LiPF6)NANANN

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Lithium‐ionBattery‐Rechargeable

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PolyvinylideneFlouride(PVDF)NANANN

StyreneButadieneRubber(SBR)NANANN

Aluminum,Steel,Nickelandotherinertmaterials NANANN



EYEPROTECTION:

Notnecessaryunderconditionsofnormaluse



SKINPROTECTION:

Notnecessaryunderconditionsofnormaluse



RESPIRATORYPROTECTION:

Notnecessaryunderconditionsofnormaluse



ENGINEERINGCONTROLS:

Notnecessaryunderconditionsofnormaluse



GENERALHYGIENECONSIDERATIONS:

Notnecessaryunderconditionsofnormaluse



EXPOSUREGUIDELINES:

Notnecessaryunderconditionsofnormaluse



SECTION9:PHYSICALANDCHEMICALPROPERTIES



Datarepresenttypicalvaluesandarenotintendedtobespecifications.NA=NotApplicable;ND=NotDetermined



Physicalstate:.................................SolidViscosity:.......................................................NA

Colour:............................................NAUpperExplosiveLimits(vol%inair):..........NA 

Odor:..............................................OdorlessLowerExplosiveLimits(vol%inair):...........NA

OdorThreshold:.............................NAVaporpressure:............................................NA

pH:.................................................NAVapordensity:..............................................NA

Melting/FreezingPoint:.................NARelativedensity:...........................................NA

VOCContent:..................................NASolubility:......................................................NA

BoilingPoint:..................................NAPartitionCoefficient:....................................NA

FlashPoint:.....................................NAAuto‐ignitionTemperature:.........................NA

EvaporationRate:...........................NADecompositionTemperature:......................NA

SpecificGravity:............................NAFlammability(solid,gas):.............................Organiccomponentswill

burnifcellisincinerated



SECTION10:STABILITYANDREACTIVITY



INCOMPATIBLEMATERIALS:

Water,heatandstrongacids.



DECOMPOSITIONPRODUCTSMAYINCLUDE:

HydrogenFluoride,PhosphorusOxides,CarbonMonoxide,CarbonDioxide,LithiumHydroxide,ManganeseOxides,Aluminum

Oxide,possiblefluoro‐compounds,Carbonsoot.



CONDITIONSTOAVOID:

Donotcrush,puncture,incinerate,immerseinwaterorheatover212°F(100°C).Steelcasingslowlydissolvesinstrongmineral

acids.



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Lithium‐ionBattery‐Rechargeable

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POLYMERIZATION:

Hazardouspolymerizationwillnotoccur.Spontaneousdecompositionwillnotoccuratnormaltemperature.

CHEMICALSTABILITY:

Thisproductisstable.



REACTIVITY:

Hazardouspolymerizationwillnotoccur.Spontaneousdecompositionwillnotoccuratnormaltemperature.



SECTION11:TOXICOLOGYINFORMATION



LIKELYROUTESOFEXPOSURE:Inhalation,EyeandSkincontact

Eyecontact,skincontact,skinabsorption,inhalationonlyifburned.Hydrofluoricacidisextremelycorrosive.Contactwith

hydrogenfluoridefumesistobeavoided.Permissibleexposurelimitis3ppm.Incaseofcontactwithhydrogenfluoridefumes,

immediatelyleavetheareaandseekfirstaidandemergencymedicalattention.Symptomsmayhavedelayedonset.Fluoride

ionspenetrateskinreadilycausingdestructionofdeeptissuelayersevenbone.Fluorideinterfereswithnerveimpulse

conductioncausingseverepainorabsenceofsensations.Immediatelyflusheyesorskinwithwaterforatleast20minutesto

neutralizetheacidityandremovesomefluoride.Removeanddestroyallcontaminatedclothingandpermeablepersonal

possessions.Beforere‐use,impermeablepossessionsshouldbesoakedinbenzalkoniumchlorideafterwashing.Following

flushingoftheaffectedareas,anicedaqueoussolutionofbenzalkoniumchlorideor2.5%calciumgluconategelshouldbe

appliedtoreactwiththefluorideion.Compressesandwrapsmaybeusedforareaswhereimmersionisnotpractical.

Medicateddressingshouldbechangedevery2minutes.Exposuretohydrofluoricacidfumessufficienttocausepainrequires

immediatehospitalizationformonitoringforpulmonaryedema.



ACUTESYMPTOMSANDEFFECTS:

Inhalation:Nofurthertoxicologicaldataknown

Eyecontact:Nofurthertoxicologicaldataknown

Skincontact:Nofurthertoxicologicaldataknown

Ingestion:Nofurthertoxicologicaldataknown



OTHER:

Nofurtherdataknown.



SECTION12:ECOLOGICALINFORMATION



ECOTOXICOLOGICALINFORMATION:

Noneinroutinehandlingofproduct.



TOXICITY:

Nodataavailable



PERSISTENCEANDDEGRADABILITY(BIOPERSISTENCY&BIODEGRADABILITY):

Noneinroutinehandlingofproduct.



POTENTIALOFBIOACCUMULATION:

Noneinroutinehandlingofproduct.



MOBILITYINSOIL:

Noneinroutinehandlingofproduct.



OTHERADVERSEEFFECTS:

Nodataavailable



Page6of858‐97‐0500

Lithium‐ionBattery‐Rechargeable

14A

SECTION13:DISPOSALCONSIDERATIONS



DISPOSAL:

Disposeinaccordancewithappropriateregulations.Alwaysconsultandobeyallinternational,federal,provincial/stateandlocal

hazardouswastedisposallaws.Somejurisdictionsrequirerecyclingofthisspentproduct.Batteryrecyclingisencouraged.

Lithiumionbatteriesaresafefordisposalinthenormalmunicipalwastestreamsincetheyarenotdefinedbythefederal

governmentashazardouswaste.However,Lithiumionbatteriesarerecyclable.



Thisproductdoesnotcontainmercury,cadmiumorLithium(metal).



DONOTINCINERATEorsubjectbatterycellstotemperaturesinexcessof212°F(100°C).



SECTION14:TRANSPORTATIONINFORMATION



U.S.DOTHAZARDOUSMATERIALREGULATIONS(RE:GROUNDTRANSPORT) 

ProperShippingDescription:

UN3480Lithium‐ionbatteries;UN3481Lithium‐ionbatteriespackedwithorcontainedinequipment;Class9.



MilwaukeeLithium‐ionbatteriesaretobeshippedincompliancewithrelevantrequirementsofHMR“49CFR173.185”.



CANADATRANSPORTDANGEROUSGOODS(RE:GROUNDTRANSPORT)

ProperShippingDescription:

UN3480Lithium‐ionbatteries;UN3481Lithium‐ionbatteriespackedwithorcontainedinequipment;Class9.



MilwaukeeLithium‐ionbatteriesaretobeshippedincompliancewithrelevantrequirementsofTDG“Part2”(Section2.43),

orTDG“Schedule2”(SpecialProvision34),asapplicable.



INTERNATIONALDANGEROUSGOODSREGULATIONS(RE:AIR,SEA,GROUNDTRANSPORT)

ProperShippingDescription:

UN3480Lithium‐ionbatteries;UN3481Lithium‐ionbatteriespackedwithorcontainedinequipment;Class9.



MilwaukeeLithium‐ionbatteriesaretobeshippedincompliancewithrelevantrequirementsofthefollowingDG

Regulations:

 ICAOTechnicalInstructionsorIATADangerousGoodsRegulations(60thEdition):PackingInstructions965;966;967

(SectionI,orSectionII,asapplicable).

 IMDGCode:PackingInstructionP903,orSpecialProvision188,asapplicable.

 UNModelRegulationsontheTransportofDangerousGoods:PackingInstructionP903,orSpecialProvision188,as

applicable.

 UNEuropeanAgreements(ADR/RID/ADN):PackingInstructionP903,orSpecialProvision188,asapplicable.

 AustralianDangerousGoods(ADG):PackingInstructionP903,orSpecialProvision188,asapplicable.



IMPORTANT:Theproperclassification,packaging,labeling,marking,anddocumentationrequirementsforshippingLithium‐ion

batteriesisdependentuponwhethertheparticularbatteriesare:

a.) Ratedat100Watt‐hours(Wh)orless;or

b.) Ratedatgreaterthan100Wh.



Generally,Lithium‐ionbatteriesrated100Whorlessare“excepted”fromcertainClass9DGrequirements.Alwayscheck

complianceofLithium‐ionbatteryconsignmentsagainstthecurrentregulationsgoverningthechosenmodeoftransport.When

indoubt,contactthecarrierorothertrainedDangerousGoodsprofessionaltoconfirmacceptability.



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Lithium‐ionBattery‐Rechargeable

14A

UN38.3BATTERYTRANSPORTATIONTESTING:

MilwaukeerechargeableLithium‐ionbatterieslistedinSection1havepassedtherelevanttransportationtestrequirementsas

describedintheUNManualofTestsandCriteria,PartIII,section38.3.



UN38.3TestReportsaremaintainedonfileatthecorporateheadquartersofMilwaukeeElectricToolCorporationlocatedat

13135W.LisbonRd.,Brookfield,WI,USA53005.



SECTION15:REGULATORYINFORMATION



GLOBALINVENTORIES



TSCA:UnitedStatesSeeSec.14.Compliantwith,relevanttransportationtestrequirementsasdescribedinthe

UNManualofTests&Criteria,PartIII,Sub‐section38.3.

DSL:CanadaSeeSec.14.Compliantwith,relevanttransportationtestrequirementsasdescribedinthe

UNManualofTests&Criteria,PartIII,Sub‐section38.3.

ECL:KoreaCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.

PICCS:PhilippinesCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.

ENCS:JapanCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.

AICS:AustraliaCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.

IECS:ChinaCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.

EINECS:EuropeanUnionCompliantwith,relevanttransportationtestrequirementsasdescribedintheUNManual

ofTests&Criteria,PartIII,Sub‐section38.3.



SARA313Information:

SARATitleIIISection313:Thisproductdoesnotcontainregulatedlevelsofanytoxicchemicalsubjecttothereporting

requirementsofSection313ofTitleIIIoftheSuperfundAmendmentsandReauthorizationActof1986(SARA)and40CFRpart

372.



CaliforniaSafeDrinkingWaterandToxicEnforcementActof1986(Proposition65)

ThisproductdoesnotcontainregulatedlevelsofanytoxicchemicalsubjecttothereportingrequirementsofCaliforniaSafe

DrinkingWaterandToxicEnforcementActof1986(Proposition65)



WHMIS:CanadianWorkplace

Thisproductdoesnotcontainregulatedlevelsofanytoxicchemicalsubjecttothereportingrequirements



SECTION16:OTHERINFORMATION



ABBREVIATIONS:

TSCA.....................ToxicSubstanceControlAct

ICAO.....................InternationalCivilAviationOrganization

IMDG......................InternationalMaritimeDangerous

OSHA....................OccupationalSafetyandHealth

IARC/NTP...............InternationalAgencyforResearchonCancer/NationalToxicologyProgram

SARA.....................SuperfundAmendmentsandReauthorizationActof1986

ACGIH...................AmericanConferenceofGovernmentalIndustrialHygienists

Page8of858‐97‐0500

Lithium‐ionBattery‐Rechargeable

14A

NIOSH/MSHA........NationalInstituteforOccupationalSafetyHealth/

 MineSafetyandHealthAdministration

WHMIS...................WorkplaceHazardousMaterialsInformationSystem



Preparedby: MilwaukeeElectricToolCorporation



ThebatteriesreferencedhereinareconsideredexemptarticlesandarenotsubjecttotheOSHAHazardCommunicationStandard;

thereforeaSDSisnotrequired.Thissheetisbeingprovidedasaservicetoourcustomers.



Theinformationandrecommendationssetfortharemadeingoodfaithandbelievedtobeaccurateasofthedateofpreparation.

MILWAUKEEELECTRICTOOLCORPORATIONmakesnowarranty,expressedorimplied,regardingtheaccuracyofthisdataorthe

resultstobeobtainedfromthe use thereto.

Milwaukee M12 User manual

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