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GMAW
The selection of the correct shielding gas for a given application
is critical to the quality of the finished weld. The criteria used to
make the selection includes, but is not restricted to, the following:
• Alloy of wire electrode.
• Desired mechanical properties of the deposited weld metal.
• Material thickness and joint design.
•
Material condition – the presence of millscale, corrosion,
r
esistant coatings, or oil.
• The mode of GMAW metal transfer.
• The welding position.
• Fit-up conditions.
• Desired penetration profile.
• Desired final weld bead appearance.
• Cost.
Under the heat of the arc, shielding gases respond in different
ways. The flow of current in the arc, and its magnitude, has a
profound effect on the behavior of the molten droplet. In some
cases, a given shielding gas will optimally lend itself to one
transfer mode, but will be incapable of meeting the needs of
another. Three basic criteria are useful in understanding the
properties of shielding gas:
• Ionization potential of the gas components
• Thermal conductivity of the shielding gas components
• The chemical reactivity of the shielding gas with the molten
weld puddle
The following discussion details the arc physics associated with
specific shielding gases, and permits the selection of the best
shielding gas for the application.
Shielding Gases
Argon and helium are the two inert shielding gases used for
protecting the molten weld pool. The inert classification indicates
that neither argon nor helium will react chemically with the
molten weld pool. However, in order to become a conductive
gas, that is, a plasma, the gas must be ionized. Different gases
require different amounts of energy to ionize, and this is
measured in terms of the ionization energy. For argon, the
ionization energy is 15.7 eV. Helium, on the other hand, has an
ionization energy of 24.5 eV. Thus, it is easier to ionize argon
than helium. For this reason argon facilitates better arc starting
than helium.
The thermal conductivity, or the ability of the gas to transfer
thermal energy, is the most important consideration for selecting
a shielding gas. High thermal conductivity levels result in more
conduction of the thermal energy into the workpiece. The
thermal conductivity also affects the shape of the arc and the
temperature distribution within the region. Argon has a lower
thermal conductivity rate — about 10% of the level for both
helium and hydrogen. The high thermal conductivity of helium
will provide a broader penetration pattern and will reduce the
depth of penetration. Gas mixtures with high percentages of
argon will result in a penetration profile with a finger-like
projection into the base material, and this is due to the lower
thermal conductivity of argon.
Inert Shielding Gases
Argon is the most commonly used inert gas. Compared to
h
elium its thermal conductivity is low. Its energy required to
give up an electron, ionization energy, is low, and this results in
the finger-like penetration profile associated with its use. Argon
supports axial spray transfer. Nickel, copper, aluminum, titanium,
and magnesium alloyed base materials use 100% argon
shielding. Argon, because of its lower ionization energy, assists
with arc starting. It is the main component gas used in binary
(two-part) or ternary (three-part) mixes for GMAW welding. It
also increases the molten droplet transfer rate.
Helium is commonly added to the gas mix for stainless and
aluminum applications. Its thermal conductivity is very high,
resulting in the broad but less deep penetration profile.
When in use, arc stability will require additions of arc voltage.
Helium additions to argon are effective in reducing the dilution of
base material in corrosion resistant applications. Helium/argon
blends are commonly used for welding aluminum greater than 1”
(25 mm) thick.
Reactive Shielding Gases
Oxygen, hydrogen, nitrogen, and carbon dioxide (CO
2
) are
reactive gases. Reactive gases combine chemically with the
weld pool to produce a desirable effect.
Carbon Dioxide (CO
2
) is inert at room temperature. In the
presence of the arc plasma and the molten weld puddle it is
reactive. In the high energy of the arc plasma the CO
2
molecule
breaks apart in a process known as dissociation. In this
process, free carbon, carbon monoxide, and oxygen release
from the CO
2
molecule. This occurs at the DC+ anode region
of the arc. At the DC- cathode region, which is invariably the
work piece for GMAW, the released elements of the CO
2
molecule undergo the process of recombination. During recom-
bination higher energy levels exist and are responsible for the
deep and broad penetration profile that characterizes the use of
carbon dioxide.
Dissociation and Recombination
During the process of dissociation, the free elements of the CO
2
molecule (carbon, carbon monoxide, and oxygen) mix with the
molten weld pool or recombine at the colder cathode region of
the arc to form, once again, carbon dioxide. The free oxygen
combines chemically with the silicon, manganese, and iron to
form oxides of silicon, manganese and iron. Formed oxides,
commonly referred to as silica islands, float to the surface of the
weld pool, then solidify into islands on the surface of the finished
weld or collect at the toes of a weld. Higher levels of carbon
dioxide (higher oxidation potential) increases the amount of slag
formed on the surface of the weld. Lower levels of carbon
dioxide (lower oxidation potential) increase the amount of alloy,
Shielding Gases for GMAW