General Finishes GF.PD User manual

General Finishes
Brand
General Finishes
Model
GF.PD
Type
User manual

This manual is also suitable for

Driftwood Milk Paint
Not available.
Liquid.
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Manufacturer
:
Relevant identified uses of the substance or mixture and uses advised against
SAFETY DATA SHEET
Driftwood Milk Paint
Conforms to HCS 2012 - United States
Identified uses
Water-based coating.
:
General Finishes
2462 Corporate Circle
East Troy, WI 53120
U.S.A.
Phone no.: 262-642-4545
Toll free no.: 1-800-783-6050
Fax no.: 262-642-4707
Web: GeneralFinishes.com
CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887
(24/7)
Section 2. Hazards identification
CARCINOGENICITY - Category 1
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard statements
:
H350 - May cause cancer.
Hazard pictograms
:
Precautionary statements
:
P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.
:
P308 + P313 - IF exposed or concerned: Get medical attention.
:
P405 - Store locked up.
:
P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.
GHS label elements
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Hazards not otherwise
classified
:
None known.
1/11
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Driftwood Milk Paint
Section 3. Composition/information on ingredients
Titanium dioxide
10 - 30
13463-67-7
Carbon black
0.1 - 1
1333-86-4
Crystalline silica, quartz
0.1 - 1
14808-60-7
Ingredient name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Other means of
identification
:
Not available.
CAS number
:
Not applicable.
Substance/mixture
Product code
:
Not available.
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes.
Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before
reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not
breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Over-exposure signs/symptoms
:
No known significant effects or critical hazards.
Potential acute health effects
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Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
No special measures are required.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
No specific fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
In case of fire, use water spray (fog), foam, dry chemical or CO
2
.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training. Keep
unnecessary and unprotected personnel from entering. Do not touch or walk through
spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
3/11
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Section 6. Accidental release measures
Methods and materials for containment and cleaning up
Small spill
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Section 8. Exposure controls/personal protection
Ingredient name
Control parameters
Occupational exposure limits
Titanium dioxide
ACGIH TLV (United States, 3/2016).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
1,2-Propylene glycol
AIHA WEEL (United States, 10/2011).
TWA: 10 mg/m³ 8 hours.
Carbon black, respirable powder
NIOSH REL (United States, 10/2013).
TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 3.5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2016).
TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction
Crystalline silica, quartz
OSHA PEL Z3 (United States, 6/2016).
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form: Respirable
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form: Respirable
Exposure limits
4/11
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Driftwood Milk Paint
Section 8. Exposure controls/personal protection
Use a properly fitted, air-purifying or supplied air respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection
:
:
:
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.
Appropriate engineering
controls
:
If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: Respirable dust
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction
Crystalline silica, respirable powder
OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf 8 hours. Form: Respirable
TWA: 10 mg/m³ 8 hours. Form: Respirable
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: Respirable dust
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction
5/11
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Driftwood Milk Paint
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Viscous.]
Not available.
1.25
Not available.
Not available.
Soluble in the following materials: cold water and hot water.
Not available.
Odor
pH
Brown.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: >98.889°C (>210°F)
Not available.
Not available.
Viscosity
Dynamic (room temperature): 2000 mPa·s (2000 cP)
Not available.
Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Not available.
Decomposition temperature
:
Not available.
VOC content
:
86.066 g/L
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
Protect from freezing.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
Reactive or incompatible with the following materials: oxidizing materials and acids.
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
6/11
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Section 11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Mutagenicity
Teratogenicity
Reproductive toxicity
Irritation/Corrosion
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Carbon black
LD50 Oral
Rat
>15400 mg/kg
-
There is no data available.
There is no data available.
There is no data available.
There is no data available.
There is no data available.
Information on the likely
routes of exposure
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation
No known significant effects or critical hazards.
:
Eye contact
:
No known significant effects or critical hazards.
Specific target organ toxicity (repeated exposure)
Name
Category
Crystalline silica, quartz
Category 1
Not determined
kidneys, respiratory tract
and testes
Aspiration hazard
Route of
exposure
Target organs
:
Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
There is no data available.
Titanium dioxide
Skin - Mild irritant
Human
-
72 hours 300 µg
Intermittent
-
Product/ingredient name
Titanium dioxide
-
2B
-
A4
-
+
Talc
-
3
-
A4
-
-
Diiron trioxide
-
3
-
A4
-
-
Carbon black, respirable powder
-
2B
-
A3
-
+
Crystalline silica, quartz
-
1
Known to be a human carcinogen.
A2
-
+
Crystalline silica, respirable powder
-
1
Known to be a human carcinogen.
A2
-
+
ACGIH
EPA
NIOSH
NTP
IARC
OSHA
Classification
7/11
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Section 11. Toxicological information
No known significant effects or critical hazards.
:
May cause cancer. Risk of cancer depends on duration and level of exposure.
:
No known significant effects or critical hazards.
:
No known significant effects or critical hazards.
:
:
No known significant effects or critical hazards.
:
No known significant effects or critical hazards.
Skin contact
Ingestion
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Acute toxicity estimates
:
No known significant effects or critical hazards.
Short term exposure
:
No known significant effects or critical hazards.
:
No known significant effects or critical hazards.
Long term exposure
:
No known significant effects or critical hazards.
There is no data available.
Section 12. Ecological information
Toxicity
Product/ingredient name
Species
Result
Exposure
Titanium dioxide
Acute EC50 5.83 mg/L Fresh water
Algae - Pseudokirchneriella subcapitata -
Exponential growth phase
72 hours
Acute LC50 3 mg/L Fresh water
Crustaceans - Ceriodaphnia dubia -
Neonate
48 hours
Acute LC50 5.5 ppm Fresh water
Daphnia - Daphnia magna - Juvenile
(Fledgling, Hatchling, Weanling)
48 hours
Acute LC50 1000 mg/L Fresh water
Fish - Pimephales promelas
96 hours
Chronic NOEC 0.984 mg/L Fresh water
Algae - Pseudokirchneriella subcapitata -
Exponential growth phase
72 hours
LogP
ow
BCF
Potential
Bioaccumulative potential
Product/ingredient name
Titanium dioxide
-
352
low
Persistence and degradability
Soil/water partition
coefficient (K
OC
)
:
Not available.
Mobility in soil
There is no data available.
8/11
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Section 12. Ecological information
Other adverse effects
:
No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered when recycling is
not feasible. This material and its container must be disposed of in a safe way. Care
should be taken when handling empty containers that have not been cleaned or rinsed
out. Empty containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.
:
Disposal methods
Section 14. Transport information
-
-
-
-
-
Not regulated.
-
-
Not regulated.
Not regulated.
-
-
-
IMDG
IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No.
No.
No.
Transport within user’s premises:
always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
:
AERG
:
Not applicable.
DOT Classification
-
-
Section 15. Regulatory information
U.S. Federal regulations
Clean Water Act (CWA) 311
: Cyclohexane
:
TSCA 8(a) PAIR
: (2-Methoxymethylethoxy)propanol; 1-(2-Butoxy-1-methylethoxy)
propan-2-ol
TSCA 8(a) CDR Exempt/Partial exemption
: Not determined
United States inventory (TSCA 8b)
: All components are listed or exempted.
9/11
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Section 15. Regulatory information
The following components are listed: Titanium dioxide; Talc, not containing asbestiform
fibres; Limestone; Diiron trioxide
WARNING:
This product contains a chemical known to the State of California to cause cancer.
WARNING:
This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
Massachusetts
:
SARA 313
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:
Not listed
Clean Air Act Section 602
Class I Substances
:
Not listed
Clean Air Act Section 602
Class II Substances
:
Not listed
DEA List I Chemicals
(Precursor Chemicals)
:
Not listed
DEA List II Chemicals
(Essential Chemicals)
:
Not listed
New York
:
None of the components are listed.
New Jersey
:
The following components are listed: Titanium dioxide; Propane-1,2-diol; Talc, not
containing asbestiform fibres; Limestone; Diiron trioxide; Carbon black
Pennsylvania
:
The following components are listed: Titanium dioxide; Propane-1,2-diol; Talc, not
containing asbestiform fibres; Limestone; Diiron trioxide; Carbon black
State regulations
SARA 302/304
:
284331.6 lbs / 129086.6 kg [27280.8 gal / 103269.2 L]
Composition/information on ingredients
Name
%
EHS
(lbs)
(lbs)
(gallons)
(gallons)
SARA 302 TPQ
SARA 304 RQ
SARA 311/312
:
Delayed (chronic) health hazard
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
Ethylene oxide
0 - 0.1
Yes.
1000
-
10
-
Titanium dioxide
10 - 30
No.
No.
No.
No.
Yes.
Carbon black
0.1 - 1
No.
No.
No.
No.
Yes.
Crystalline silica, quartz
0.1 - 1
No.
No.
No.
No.
Yes.
There is no data available.
10/11
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Section 15. Regulatory information
Titanium dioxide
Yes.
No.
No.
No.
Carbon black
Yes.
No.
No.
No.
Crystalline silica, quartz
Yes.
No.
No.
No.
Ethylene oxide
Yes.
Yes.
Yes.
Yes.
1,4-Dioxane
Yes.
No.
Yes.
No.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
Section 16. Other information
History
Procedure used to derive the classification
Classification
Justification
CARCINOGENICITY - Category 1
Expert judgment
Date of issue mm/dd/yyyy
Prepared by
:
Date of previous issue
Version
:
:
:
2
11/15/2016
06/15/2014
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
KMK Regulatory Services Inc.
11/11
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General Finishes GF.PD User manual

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