No. HK2002
MATERIAL SAFETY DATA SHEET
Matsushita Electric Industrial CO.,LTD Office Equipment Division
9-1, Hiraide Kogyo Danchi, Utsunomiya City, Tochigi 321, Japan
Phone No. Japan 028-663-3221, Fax No. Japan 028-662-8393
Revision date : October 1, 1996
SECTION 1 PRODUCT IDENTIFICATION
PRODUCT NAME : Photoconductor for FP-77series,
PRODUCT NO. : FQ-HK20 (FFPGJ0007),
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
PROPORTION
INGREDIENTS CAS #
(% by wt.) OSHA PEL ACGIH TLV OTHER
LIMITS
Substrate
Aluminum alloy > 98 None established None established None
Coating layer
Binder layer < 1 None established None established None
Organic < 1 None established None established None
semiconductor
SECTION 3 HAZARD IDENTIFICATION
EMERGENCY OVERVIEW : Dark red colored aluminum cylinder, with no oder.
POTENTIAL HEALTH EFFECTS :
INHALATION EFFECTS : Not applicable under intended use.
INGESTION EFFECTS : Not applicable under intended use.
EYE EFFECTS : Not applicable under intended use.
SKIN EFFECTS :No corroding or irritating effect is expected.
CHRONIC EFFECTS : Not identified.
MEDICAL CONDITIONS GENERALLY KNOWN TO BE AGGRAVATED BY EXPOSURE : Not identified.
1/4
No. HK2002
SECTION 4 FIST AID MEASURES
SKIN CONTACT : In case of contact, wash skin with water and soap .
INGESTION : If needed, get medical attention.
INHALATION : If needed, get medical attention.
EYE CONTACT : Flush with plenty of water.
NOTE TO PHYSICIANS : None
SECTION 5 FIRE FIGHTING MEASURES
FIRE FIGHTING MEASURES :
EXTINGUISHING MEDIA : CO
2
, Dry chemical, Foam or Water.
UNSUITABLE EXTINGUISHING MEDIA : None
SPECIAL FIRE FIGHTING PROCEDURES : None
UNUSUAL FIRE AND EXPLOSION HAZARDS : None
FIRE AND EXPLOSIVE PROPERTIES :
FLASH POINT : Not applicable.
FLAMMABLE LIMITS : Not applicable.
AUTOIGNITION TEMPERATURE : Not applicable.
FLAMMABILITY : Not flammable.
AUTOFLAMMABILITY : None
EXPLOSIVE PROPERTIES : None
OXIDIZING PROPERTIES : None
HAZARDOUS COMBUSTION PRODUCTS : Carbon monoxide and Carbon dioxide.
OTHER PROPERTIES : None
SECTION 6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS : Not applicable under intended use.
ENVIRONMENTAL PRECAUTIONS : Not applicable under intended use.
METHOD FOR CLEANING UP : Not applicable under intended use.
SECTION 7 HANDLING AND STORAGE
HANDLING : None of safe handling advice.
STORAGE : Keep at temperature not exceeding 32°C.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE GUIDELINES : None
ENGINEERING CONTROLS : Not required.
PERSONAL PROTECTION EQUIPMENTS :
SKIN PROTECTION : Not required.
RESPIRATORY PROTECTION : Not required.
EYE/FACE PROTECTION : Not required.
2/4
No. HK2002
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE : Dark red colored aluminum cylinder
ODOR : No odor
BOILING POINT (°C) : Not applicable
MELTING POINT (°C) : 100°C or higher
DECOMPOSITION TEMPERATURE : No data available
VAPOR PRESSURE (mm Hg.) : Negligible
VAPOR DENSITY (AIR = 1) : Not applicable
DENSITY (AIR = 1) : No data available
pH : Not applicable
SOLUBILITY IN WATER : Negligible
FAT SOLUBILITY : Partially soluble in ketones, esters and aromatic solvents.
PARTITION COEFFICIENT : Not soluble in water and n-octanol
PERCENT VOLATILE : Negligible
EVAPORATION RATE : Not applicable
SECTION 10 STABILITY AND REACTIVITY
STABILITY : Stable
CONDITIONS TO AVOID : None
MATERIALS TO AVOID : None
HAZARDOUS DECOMPOSITION PRODUCTS : None
HAZARDOUS POLYMERIZATION : Will not occur.
CONDITIONS TO AVOID : None
SECTION 11 TOXICOLOGICAL INFORMATION
ACUTE TOXICITY :
SKIN : No data available.
INGESTION : No data available.
INHALATION : No data available.
EYES : No data available.
SENSITIZATION : No data available.
MUTAGENICITY : All components of the photoconductive coating have been subjected to
the "Ames test", and shown to have no harmful effect.(Test Negative)
REPRODUCTIVE TOXICITY : No data available.
CARCINOGENICITY : No carcinogen or potential carcinogen, according to IARC Monographs,
NTP and OSHA(USA) regulation.
OTHERS : None
3/4
No. HK2002
SECTION 12 ECOLOGICAL INFORMATION
MOBILITY : No data available
PERSISTENCE : No data available
BIOACCUMULATION : No data available
ECOTOXICITY : No data available
OTHER ADVERSE EFFECTS : No data available
SECTION 13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD : Dispose under conditions which meet all federal, state and
local environmental control regulations.
SECTION 14 TRANSPORT INFORMATION
UN NUMBER : None
UN SHIPPING NAME : None
UN CLASSIFICATION : None
UN PARKING GROUP : None
SPECIAL PRECAUTIONS : None
SECTION 15 REGULATORY INFORMATION
No information
SECTION 16 OTHER INFORMATION
No information
These data described solely the safety requirements for the product and are based on the present
state of our knowledge. They provide no guarantee of the product described within the meaning of
the legal guarantee regulations.
4/4
No. TK2002
MATERIAL SAFETY DATA SHEET
Matsushita Electric Industrial CO.,LTD Office Equipment Division
9-1, Hiraide Kogyo Danchi, Utsunomiya City, Tochigi 321, Japan
Phone No. Japan 028-663-3221, Fax No. Japan 028-662-8393
Revision date : October 1, 1996
SECTION 1 PRODUCT IDENTIFICATION
PRODUCT NAME : Dry Toner for FP-77series,
PRODUCT NO. : FQ-TK20, FQ-TK10, FQ-TK05,
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
PROPORTION
INGREDIENTS CAS # (% by wt.) OSHA PEL ACGIH TLV OTHER
LIMITS
Styrene acrylate 25767-47-9 80 - 90 None established None established None
copolymer
Carbon black 1333-86-4 5 - 10 3.5 mg/m
3
3.5 mg/m
3
None
Polypropylene 9003-07-0 1 - 5 None established None established None
Polyethylene 68441-17-8 1 - 5 None established None established None
Organic pigment 116810-46-9 1 - 5 15 mg/m
3
15 mg/m
3
None
Silica 7631-86-9 < 1 80 mg/m
3
10 mg/m
3
None
SECTION 3 HAZARD IDENTIFICATION
EMERGENCY OVERVIEW : Fine black powder(mean dia. is about 8.5µm). Slight odor.
POTENTIAL HEALTH EFFECTS :
EYE EFFECTS : Mild irritant.
SKIN EFFECTS : None currently known.
INGESTION EFFECTS : May be harmful if swallowed.
INHALATION EFFECTS : Minimal respiratory tract irritation may occur as with exposure to large
amounts of any non-toxic dust. May cause cough and raise phlegm.
CHRONIC EFFECTS : Not aware of any health effects associated with toner under its intended use.
CARCINOGENICITY : Carbon black is reclassified as a group 2B by IARC, but inhalation test using
a typical toner showed no association between toner exposure and animal tumors.
1/4
No. TK2002
SECTION 4 FIST AID MEASURES
EYE CONTACT : Any material that contacts the eye should be washed out immediately with water.
Get medical attention if symptoms are occurred.
SKIN CONTACT : Wash after each contact. Get medical attention if symptoms are occurred.
INHALATION : If symptomatic, remove to fresh air. Get medical attention if symptoms persist.
IF SWALLOWED : If swallowed, drink 1 or 2 glasses of water and immediately induce vomiting.
Get medical attention.
SECTION 5 FIRE FIGHTING MEASURES
FLASH POINT : Not applicable.
FLAMMABLE LIMITS : Not applicable.
EXTINGUISHING MEDIA : Water, Dry chemical, Foam.
HAZARDOUS COMBUSTION PRODUCTS : Carbon monoxide, Carbon dioxide and Smoke.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Minimize the release of particulate. Wear personal protective equipment. Sweep up or vacuum
spilled toner and carefully transfer into sealed waste container. Sweep slowly to minimize
generation of dust during cleanup. If a vacuum is used, the motor must be rated as dust tight.
Residue can be removed with soap and water. Garments may be washed or dry cleaned, after
removal of loose toner.
SECTION 7 HANDLING AND STORAGE
HANDLING : Avoid prolonged inhalation of excessive dust and contact with eyes.
Keep out of reach children.
PREVENTION OF FIRE AND EXPLOSION : This material is capable of creating a dust explosion.
Avoid contact with ignition sources ex.heat, fire, etc.
STORAGE : Store in a cool and dry place. Keep away from strong oxidizers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS : Good general ventilation is recommended.
RESPRIRATORY PROTECTION : Not required under normal conditions. For use other than in normal
operating procedures (such as in the event of large spill), goggles and
respirators may be required.
SKIN PROTECTION : Not required under normal conditions.
EYE PROTECTION : Not required under normal conditions.
EXPOSURE LIMITS : ACGIH TLV 10mg/m
3
(Total Dust),
OSHA PEL 15mg/m
3
(Total Dust), 5mg/m
3
(Respirable Dust).
2/4
No. TK2002
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE : Fine black powder
ODOR : Slight odor
pH : Not applicable
VAPOR PRESSURE (mm Hg.) : Not applicable
VAPOR DENSITY (AIR = 1) : Not applicable
EVAPORATION RATE : Not applicable
BOILING POINT (°C) : Not applicable
MELTING POINT (°C) : 140 - 160 °C
SOLUBILITY IN WATER : Insoluble in water
SPECIFIC GRAVITY (H2O = 1) : 1.1
SECTION 10 STABILITY AND REACTIVITY
STABILITY : Stable
INCOMPATIBILITY : Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS : Carbon monoxide, Carbon dioxide and Smoke.
HAZARDOUS POLYMERIZATION : Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
INHALATION : Finely divided solid. Avoid exposure to dust.
EYES : No specific hazard known. May cause temporary irritation.
SKIN : Low hazard for recommended handling.
INGESTION : Expected to be a low ingestion hazard.
MUTAGENICITY : Negative in the Ames test(TA98,TA98+S9,TA100,TA100+S9,TA1535,TA1535+S9,TA1537,
TA1537+S9,WP2uvrA and WP2uvrA+S9)
CARCINOGENICITY :
In 1996,the IARC revaluated carbon black as a Group 2 carcinogen (possible human carcinogen).
This evaluation is given to carbon black for which there is inadequate human evidence, but
sufficient animal evidence. The latter is based upon the development of lung tumors in rat
receiving chronic inhalation exposures to free carbon black at level that induce particle
overload of the lung.
Studies performed in animal models other than rats have not demonstrated an association
between carbon black and lung tumors. Moreover, a two-years cancer bioassay using a typical
toner preparation containing carbon black demonstrated no association between toner exposure
and tumor development in rats.
CHRONIC EFFECTS :
In a study in rats by chronic inhalation exposure to a typical toner, a mild to moderate
degree of lung fibrosis was observed in 92% of the rats in the high concentration(16mg/m
3
)
exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the
middle(4mg/m
3
) exposure group. But no pulmonary change was reported in the lowest(1mg/m
3
)
exposure group, the most relevant level to potential human exposures.
3/4
No. TK2002
SECTION 12 ECOLOGICAL INFORMATION
None known.
SECTION 13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD : When disposing of the waste or recovered material, consult federal,
state and/or local regulations for the proper disposal method.
SECTION 14 TRANSPORT INFORMATION
UN CLASS : Not regulated.
DOT CLASS : Not regulated.
TDG CLASS : Not regulated.
SECTION 15 REGULATORY INFORMATION
USA INFORMATION :
TSCA(Toxic Substance Control Act): All chemical substances in this product comply with all
applicable rules or order under TSCA.
SECTION 16 OTHER INFORMATION
REFERNCES :
IARC(1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol.65, Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds, Lyon,
pp.149-261.
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.Mackenzie,
P.Morrow, U.Mohr, S.Takenaka, and R.Mermelstein (1991) Pulmonary Response to Toner upon
Chronic Inhalation Exposure in rats. Fundamental and Applied Toxicology 17, pp.280-299.
Information on this data sheet represents our current data and best opinion as to the proper use in
handling of this product under normal conditions.
4/4
No. ZK2002
MATERIAL SAFETY DATA SHEET
Matsushita Electric Industrial CO.,LTD Office Equipment Division
9-1, Hiraide Kogyo Danchi, Utsunomiya City, Tochigi 321, Japan
Phone No. Japan 028-663-3221, Fax No. Japan 028-662-8393
Revision date : October 1, 1996
SECTION 1 PRODUCT IDENTIFICATION
PRODUCT NAME : Developer for FP-77series,
PRODUCT NO. : FQ-ZK20, FQ-ZK10,
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
PROPORTION
INGREDIENTS CAS # (% by wt.) OSHA PEL ACGIH TLV OTHER
LIMITS
Styrene acrylate 25767-47-9 1 - 5 None established None established None
copolymer
Carbon black 1333-86-4 < 1 3.5 mg/m
3
3.5 mg/m
3
None
Ferrite 1309-37-1 None established None established None
1314-13-2 95 - 99 15 mg/m
3
10 mg/m
3
None
1317-38-0 None established None established None
1309-48-4 None established None established None
Silica 7631-86-9 < 1 80 mg/m
3
10 mg/m
3
None
SECTION 3 HAZARD IDENTIFICATION
EMERGENCY OVERVIEW : Fine black powder. Slight odor.
POTENTIAL HEALTH EFFECTS :
EYE EFFECTS : Mild irritant.
SKIN EFFECTS : None currently known.
INGESTION EFFECTS : May be harmful if swallowed.
INHALATION EFFECTS : Minimal respiratory tract irritation may occur as with exposure to large
amounts of any non-toxic dust. May cause cough and raise phlegm.
CHRONIC EFFECTS / CARCINOGENICITY : Not aware of any health effects associated with developer
under its intended use.
1/4
No. ZK2002
SECTION 4 FIST AID MEASURES
EYE CONTACT : Any material that contacts the eye should be washed out immediately with water.
Get medical attention if symptoms are occurred.
SKIN CONTACT : Wash after each contact. Get medical attention if symptoms are occurred.
INHALATION : If symptomatic, remove to fresh air. Get medical attention if symptoms persist.
IF SWALLOWED : If swallowed, drink 1 or 2 glasses of water and immediately induce vomiting.
Get medical attention.
SECTION 5 FIRE FIGHTING MEASURES
FLASH POINT : Not applicable.
FLAMMABLE LIMITS : Not applicable.
EXTINGUISHING MEDIA : Water, Dry chemical, Foam.
HAZARDOUS COMBUSTION PRODUCTS : Carbon monoxide, Carbon dioxide and Smoke.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Minimize the release of particulate. Wear personal protective equipment. Sweep up or vacuum
spilled developer and carefully transfer into sealed waste container. Sweep slowly to minimize
generation of dust during cleanup. If a vacuum is used, the motor must be rated as dust tight.
Residue can be removed with soap and water. Garments may be washed or dry cleaned, after
removal of loose developer.
SECTION 7 HANDLING AND STORAGE
HANDLING : Avoid prolonged inhalation of excessive dust and contact with eyes.
Keep out of reach children.
PREVENTION OF FIRE AND EXPLOSION : This material is capable of creating a dust explosion.
Avoid contact with ignition sources ex.heat, fire, etc.
STORAGE : Store in a cool and dry place. Keep away from strong oxidizers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS : Good general ventilation is recommended.
RESPRIRATORY PROTECTION : Not required under normal conditions. For use other than in normal
operating procedures (such as in the event of large spill), goggles and
respirators may be required.
SKIN PROTECTION : Not required under normal conditions.
EYE PROTECTION : Not required under normal conditions.
EXPOSURE LIMITS : ACGIH TLV 10mg/m
3
(Total Dust),
OSHA PEL 15mg/m
3
(Total Dust), 5mg/m
3
(Respirable Dust).
2/4
No. ZK2002
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE : Fine black powder
ODOR : Slight odor
pH : Not applicable
VAPOR PRESSURE (mm Hg.) : Not applicable
VAPOR DENSITY (AIR = 1) : Not applicable
EVAPORATION RATE : Not applicable
BOILING POINT (°C) : Not applicable
MELTING POINT (°C) : Not applicable
SOLUBILITY IN WATER : Insoluble in water
SPECIFIC GRAVITY (H2O = 1) : 2.5
SECTION 10 STABILITY AND REACTIVITY
STABILITY : Stable
INCOMPATIBILITY : Strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS : Carbon monoxide, Carbon dioxide and Smoke.
HAZARDOUS POLYMERIZATION : Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
INHALATION : Finely divided solid. Avoid exposure to dust.
EYES : No specific hazard known. May cause temporary irritation.
SKIN : Low hazard for recommended handling.
INGESTION : Expected to be a low ingestion hazard.
MUTAGENICITY : Negative in the Ames test(TA98,TA98+S9,TA100,TA100+S9,TA1535,TA1535+S9,TA1537,
TA1537+S9,WP2uvrA and WP2uvrA+S9)
CARCINOGENICITY :
In 1996,the IARC revaluated carbon black as a Group 2 carcinogen (possible human carcinogen).
This evaluation is given to carbon black for which there is inadequate human evidence, but
sufficient animal evidence. The latter is based upon the development of lung tumors in rat
receiving chronic inhalation exposures to free carbon black at level that induce particle
overload of the lung.
Studies performed in animal models other than rats have not demonstrated an association
between carbon black and lung tumors. Moreover, a two-years cancer bioassay using a typical
toner preparation containing carbon black demonstrated no association between toner exposure
and tumor development in rats.
CHRONIC EFFECTS :
In a study in rats by chronic inhalation exposure to a typical toner, a mild to moderate
degree of lung fibrosis was observed in 92% of the rats in the high concentration(16mg/m
3
)
exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the
middle(4mg/m
3
) exposure group. But no pulmonary change was reported in the lowest(1mg/m
3
)
exposure group, the most relevant level to potential human exposures.
3/4
No. ZK2002
SECTION 12 ECOLOGICAL INFORMATION
None known.
SECTION 13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD : When disposing of the waste or recovered material, consult federal,
state and/or local regulations for the proper disposal method.
SECTION 14 TRANSPORT INFORMATION
UN CLASS : Not regulated.
DOT CLASS : Not regulated.
TDG CLASS : Not regulated.
SECTION 15 REGULATORY INFORMATION
USA INFORMATION :
TSCA(Toxic Substance Control Act): All chemical substances in this product comply with all
applicable rules or order under TSCA.
SECTION 16 OTHER INFORMATION
REFERNCES :
IARC(1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,
Vol.65, Printing Process and Printing Inks, Carbon Black and Some Nitro Compounds, Lyon,
pp.149-261.
H.Muhle, B.Bellmann, O.Creutzenberg, C.Dasenbrock, H.Ernst, R.Kilpper, J.C.Mackenzie,
P.Morrow, U.Mohr, S.Takenaka, and R.Mermelstein (1991) Pulmonary Response to Toner upon
Chronic Inhalation Exposure in rats. Fundamental and Applied Toxicology 17, pp.280-299.
Information on this data sheet represents our current data and best opinion as to the proper use in
handling of this product under normal conditions.
4/4
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