3M Dynamar™ High Performance Rubber Additive RA 5300 User guide

Dynamar™ High Performance Rubber Additive RA 5300
3M
Brand
3M
Model
Dynamar™ High Performance Rubber Additive RA 5300
Type
User guide
1 × 6 1 × 8 16 × 9
8.5 x .5
11 × 17 (Tabloid)8 × 8 (Square)8.5 × 11 (Letter)
Compounding
Guide
3M
™
Dyneon
™
Fluoroelastomers
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
3M
™
Dyneon
™
Fluoroelastomers
Compounding
Fluoroelastomers
Introduction 3
General Compounding 3
General Compounding Ingredients 3
Bases 3
Changes in Properties with Variations in MgO/Ca(OH)
2
Ratios and Carbon Black N990 Levels 4
Using FE 5640Q (Table) 4
FE 5640Q Contour Plots 5-6
Using FE 5840Q (Table) 7
FE 5840Q Contour Plots 8-9
Filler Systems 10
Eect of Filler Level (Non-black) on FE 5642 (Table) 11-12
Compounding FE 5642 with Various Fillers (Non-black) (Table) 13
Low Durometer Compounds (Table) 14-15
Cure Systems/Eects of Cure Systems (Table) 16
Processing Aids (Table) 17
Pigments 17
Blending Incorporated Cure Gums with Raw Gum (Table) 18
Blending with Synthetic Elastomers (Table) 19
Eects of Crosslink Density on Bisphenol Cure FKM (Table) 20
Eects of Zinc Oxide on Various Peroxide Cure FKM (Table) 21
Eects of Varying Levels of Co-Agents on Peroxide Cure FKM (FPO 3730) (Table) 22
Product Numbering System Codes 23
Compounding for O-Ring Applications 24
Compounding for Molded Goods Applications 25
Compounding for Extrusion Processes 26
Compounding for Calendering Processes 27
Compounding for Metal Adhesion 27
Safety and Toxicology 28
2
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
3
Introduction
Components created with 3M
™
Dyneon
™
Fluoroelastomer compounds have the potential to
increase the durability, reliability, and safety of your products – provided that they are made
using the proper materials and processes for the application at hand. Variations in the ratios
of inorganic bases, ller systems and cure systems used in compounding can yield signicant
control over the physical and rheological properties of the resulting compounds – including
properties such as mold ow and mold release that are critical for many applications.
This manual provides general guidelines that can be used as reference in compounding
uoroelastomers. In addition to data regarding the physical properties yielded by various
compounds and processes, the eects of potential contamination and the general
requirements of certain types of applications (such as O-rings, molded goods, and extruded
compounds) are also discussed. For more specic guidelines for the materials used in specic
applications, refer to the 3M
™
Dyneon
™
Fluoroelastomer Recipe Book.
General Compounding
The basics of choosing the polymer and cure system and compounding those systems with the
proper acid acceptors and llers to fulll the rheological, physical and processing requirements
are, in general, relatively simple. This is due to the limited number of ingredients that are able to
withstand the harsh chemical or thermal environments that uoroelastomers are exposed to.
General Compounding Ingredients (PHR)*
Fluoroelastomer 100
Acid Acceptor(s) 6-20
Filler 0-80
Processing Aids 0-2
Curatives (May be incorporated in polymer) 1-4
Bases
(Acid Acceptors)
Inorganic bases commonly used in compounding
uoroelastomers include the following:
CaO Calcium Oxide, HP-XL HallStar
®
Ca(OH)
2
Calcium Hydroxide, HP-XL HallStar
®
MgO Magnesium Oxide, Elastomag
®
170
MgO Magnesium Oxide, Maglite Y HallStar
®
MgO Magnesium Oxide, Maglite D HallStar
®
ZnO Zinc Oxide, USP #1
Inorganic bases aect both the rheological and the physical properties. The best balance of
properties will be achieved by using a combination of calcium hydroxide and magnesium oxide.
The following tables illustrate the change in properties resulting from variations in the ratio of
calcium hydroxide and magnesium oxide.
The general compounding data was generated in our Application and Product Development
Laboratory and should be used only as a guide for compounding. Potential dierences may
arise due to dierences in raw materials and processing techniques. Materials should be
processed and evaluated in the consumer’s facility to verify the properties.
*Parts per Hundred Rubber
Note:
The purpose of this guide
is to provide basic information to
product users for use in
evaluating, processing, and
troubleshooting their use of
certain 3M products. The
information provided is general
or summary in nature and is
oered to assist the user. The
information is not intended to
replace the user’s careful
consideration of the unique
circumstances and conditions
involved in its use and processing
of 3M products. The user is
responsible for determining
whether this information is
suitable and appropriate for the
user’s particular use and intended
application. The user is solely
responsible for evaluating third
party intellectual property rights
and for ensuring that user’s use
and intended application of 3M
product does not violate any third
party intellectual property rights.
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Changes in Properties with Varying Ratios of Ca(OH)
2
and MgO and Levels of Carbon Black
N990 Using FE 5640Q
(Dumbbell Test Specimens)
Compound Formulations, phr (Eect of Ca(OH)
2
/MgO Ratios and N990 level using FE 5640Q)
FE 5640Q 100 100 100 100 100 100 100 100 100 100
MT Black (N990) 55 5 5 30 55 5 55 5 55 30
Ca(OH)
2
HP-XL HallStar
®
9 3 3 6 9 9 3 9 3 0
MgO, Elastomag
®
170 0 0 6 3 6 6 0 0 6 18
Total Parts 164 108 114 139 170 120 158 114 164 148
MDR, 12 minutes @ 177°C (350°F)
ML, in-lbs 2.1 0.7 0.9 1.4 2.9 1.1 1.9 0.8 2.2 2.0
MH, in-lbs 34.2 11.1 13.4 24.2 39.4 13.8 37.8 12.5 39.0 19.6
ts2, minutes 1.6 7.6 3.8 2.4 1.1 2.1 3.5 3.1 1.9 1.8
t'50, minutes 2.4 8.3 4.3 3.0 1.8 2.3 6.1 3.3 3.5 3.2
t'90, minutes 3.5 11.4 6.4 4.5 2.9 3.2 8.9 4.8 5.4 5.9
Press Cure, 10 minutes @ 177°C (350°F)
15 Min
Tensile, psi 1416 1039 1343 1547 1505 1629 1268 1318 1514 1717
Elongation, % 271 318 315 295 214 326 319 312 320 412
Modulus 100%, psi 948 186 237 623 1027 296 812 226 948 580
Hardness, Type A, pts 88 53 57 76 89 60 87 56 88 75
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 2237 1069 1745 2303 1748 2180 2050 1606 2466 2473
Elongation, % 184 292 289 235 125 280 203 275 186 250
Modulus 100%, psi 1223 188 249 758 1394 314 1126 252 1271 739
Hardness, Type A, pts 91 54 58 76 91 61 91 58 91 79
Specic Gravity 1.84 1.85 1.90 1.88 1.90 1.90 1.84 1.86 1.87 1.91
Tear Die C on Post Cure, 16 hours @ 232°C (450°F)
Tear, ppi 199 98 114 172 186 136 198 123 201 187
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139"
O-ring
24 13 12 15 24 13 19 12 17 18
Air Aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, % change -27 -6 -14 -23 -24 -25 -19 -17 -30 -33
Elongation, % change 7 21 31 22 11 13 3 24 17 40
Modulus 100%, psi -28 -27 -34 -27 -28 -14 -26 -29 -30 -27
Hardness, Type A, pts change 1 -6 -6 2 2 -1 1 -5 1 1
Note: MgO, Ca(OH)
2
and N990 in phr
4
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
5
Note: MgO, Ca(OH)
2
and N990 in phr
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
<
22.5
22.5 23.0
23.0 23.5
23.5 24.0
24.0 24.5
24.5 25.0
25.0
MH
MH (in-lb) vs Levels of Metal Oxide
Hold Values
N990 30
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
<
2
2 3
3 4
4 5
5 6
6
T50
Hold Values
N990 30
t'50 (min) vs Levels of Metal Oxide
FE 5640Q Contour Plots
3M
™
Dyneon
™
Fluoroelastomer FE 5640Q is a 66% Fluorine dipolymer of vinyline uoride and hexauoropropylene. A design of
experiments (DOE) was run using FE 5640Q varying the levels of carbon black MT N990, Ca(OH)
2
HP-XL and MgO Elastomag
®
170. The levels of these variables range as: carbon black MT N990, from 5 to 55 phr, Ca(OH)
2
HP-XL, from 3 to 9 phr and MgO
Elastomag 170, from 0 to 6 phr. Data collected during the experiment included: cure rheology and physical properties on press
(10 minutes @ 177°C) and post cure (16 hours @ 232°C) test sheets, Die C tear strength after post cure (16 hours @ 232°C),
compression set after post cure (70 hours @ 200°C, 0.139� O-rings) and air aging (70 hours @ 270°C). Contour plots were
generated holding the carbon black level constant at 30 phr.
MgO
Ca(
OH
)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
<
210
210 220
220 230
230 240
240 250
250
Post Cure
Elongation
Hold Values
N990 30
Post Cure Elongation (%) vs Levels of Metal Oxide
Mg
O
Ca(
OH
)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
<
2000
2000 2100
2100 2200
2200 2300
2300 2400
2400 2500
2500
Post Cure Tensile (psi) vs Levels of Metal Oxide
Post Cure
Tensile
Hold Values
N990 30
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
N990 30
Hold Values
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
<
14
14 15
15 16
16 17
17
Compression
Set
Compression Set (%) vs Levels of Metal Oxide
Hold Values
N990 30
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
<
162
162 164
164 166
166 168
168 170
170 172
172
Tear (ppi) vs Levels of Metal Oxide
Tear (ppi)
N990 30
Hold Values
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
<
76
76 77
77 78
78 79
79 80
80 81
81
Hardness
Hardness vs Levels of Metal Oxide
Note: MgO, Ca(OH)
2
and N990 in phr
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
<
700
700 750
750 800
800 850
850
Hold Values
N990 30
Post Cure Modulus (psi) vs Levels of Metal Oxide
Post Cure
Modulus
FE 5640Q Contour Plots
6
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Changes in Properties with Varying Ratios of Ca(OH)
2
and MgO Using FE 5840Q
(Dumbbell Test Specimens)
Compound Formulations, phr (Eect of Ca(OH)
2
/MgO Ratios Using FE 5840Q)
FE 5840Q 100 100 100 100 100
MT Black (N990) 30 30 30 30 30
Ca(OH)
2
HP-XL, HallStar
®
3 6 9 9 3
MgO, Elastomag
®
170 0 3 6 0 6
Total Parts 133 139 145 139 139
MDR, 12 minutes @ 177°C (350°F)
ML, in-lbs 0.6 1.0 1.4 1.0 0.9
MH, in-lbs 11.1 24.3 27.2 22.6 25.0
ts2, minutes 4.4 2.3 1.4 2.0 2.3
t'50, minutes 5.2 2.8 1.7 2.4 2.9
t'90, minutes 7.1 3.9 2.3 3.3 3.8
Press Cure, 10 minutes @ 177°C (350°F)
Tensile, psi 1173 1420 1343 1248 1345
Elongation, % 625 412 254 387 338
Modulus 100%, psi 394 658 849 626 711
Hardness, Type A, pts 74 82 81 81 79
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 1521 2222 2188 1964 1952
Elongation, % 402 302 229 285 256
Modulus 100%, psi 490 774 932 770 770
Hardness, Type A, pts 81 88 88 88 84
Tear Die C on Post Cure, 16 hours @ 232°C (450°F)
Tear, ppi 194 191 189 191 170
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139" O-ring 60 36 39 39 36
Air Aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, % change -54 -52 -48 -52 -54
Elongation, % change 73 56 44 69 87
Modulus 100%, % change -34 -39 -38 -42 -47
Hardness, Type A, pts change -1 -1 0 -1 -2
Note: MgO, Ca(OH)
2
and N990 in phr
7
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
8
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
<
12
12 16
16 20
20 24
24 28
28
MH (in-lb) vs Levels of Metal Oxide
MH
(in-lb)
N990 30
Hold Values
Note: MgO, Ca(OH)
2
and N990 in phr
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
–
<
2.0
2.0 2.5
2.5 3.0
3.0 3.5
3.5 4.0
4.0 4.5
4.5 5.0
5.0
T50 (min)
t'50 (min) vs Levels of Metal Oxide
N990 30
Hold Values
FE 5840Q Contour Plots
3M
™
Dyneon
™
Fluoroelastomer FE 5840Q is a 70% Fluorine terpolymer of vinyline uoride, hexauoropropylene and
tetrauoroethylene. A design of experiments (DOE) was run using FE 5840Q varying the levels of Ca(OH)
2
HP-XL and MgO
Elastomag
®
170. The levels of these variables range as: Ca(OH)
2
HP-XL from 3 to 9 phr and MgO Elastomag 170 from 0 to 6 phr,
holding the carbon black (N990) level constant at 30 phr. Data collected during the experiment included: cure rheology and
physical properties on press (10 minutes @ 177°C) and post cure (16 hours @ 232°C) test sheets, Die C tear strength after post
cure (16 hours @ 232°C), compression set after post cure (70 hours @ 200°C, 0.139� O-rings) and air aging (70 hours @ 270°C).
Contour plots were generated holding the carbon black level constant at 30 phr.
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
–
<
1600
1600 1700
1700 1800
1800 1900
1900 2000
2000 2100
2100 2200
2200
Tensile, psi
Post Cure Tensile (psi) vs Levels of Metal Oxide
N990 30
Hold Values
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
–
<
250
250 275
275 300
300 325
325 350
350 375
375 400
400
Elongation
%
Post Cure Elongation (%) vs Levels of Metal Oxide
N990 30
Hold Values
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
<
175
175 180
180 185
185 190
190 195
195
Tear (ppi) vs Levels of Metal Oxide
Tear (ppi)
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
<
82
82 84
84 86
86 88
88
Hardness
Hardness vs Levels of Metal Oxide
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
–
–
<
30
30 35
35 40
40 45
45 50
50 55
55 60
60
Compression
Set
%
Compression Set (%) vs Levels of Metal Oxide
Note: MgO, Ca(OH)
2
and N990 in phr
MgO
Ca(OH)
2
6543210
9
8
7
6
5
4
3
>
–
–
–
–
<
500
500 600
600 700
700 800
800 900
900
100%
Modulus,
psi
Post Cure Modulus (psi) vs Levels of Metal Oxide
FE 5840Q Contour Plots
9
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
10
Filler Systems
Black ASTM Code
MT Medium Thermal N990
SRF Semi-Reinforcing Furnace N774 and N762
HAF High Abrasion Furnace N326 and N330
Non-Black (Mineral) Common Trade Names
Fine Ground Silica Min-U-Sil
®
(5 micron)
Oxides Mapico
®
Tan-10 (Fe
2
O
3
• ZnO)
Calcium Carbonate, CaCO
3
Albacar
®
5970
Barium Sulfate, BaSO
4
Huberbite
®
10
Calcium Metasilicate NYAD
®
400
Zinc Oxide, ZnO USP #1
Titanium Dioxide, TiO
2
Sakai Chemical A-110
Mistron CB Cyprubond
Silicone Dioxide Aerosil
®
R972
Zinc Sulde, ZnS Sachtolith L
Carbon Black Comparison Table (for equivalent hardness)
1 part N330 2.5 parts N990
1 part N550 2.4 parts N990
1 part N660 2.0 parts N990
1 part N774 1.9 parts N990
1 part N762 1.6 parts N990
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Eect of Filler Level (Non-Black)
3M
™
Dyneon
™
Fluoroelastomer FE 5642 formulated to various durometers with various non-black llers.
55±5 Durometer 60±5 Durometer
Compound Recipe 1 2 3 4 5 6 1 2 3 4 5 6
FE 5642 100 100 100 100 100 100 100 100 100 100 100 100
Ca(OH)
2
HP-XL, Hallstar
®
6 6 6 6 6 6 6 6 6 6 6 6
MgO, Elastomag
®
170 3 3 3 3 3 3 3 3 3 3 3 3
Min-U-Sil
®
(5 microns) 10 20
Zinc Oxide, USP #1 25 45
NYAD
®
400 10 22
Calcium Carbonate, Albacar
®
5970 10 22
Mapico
®
Tan 10A 15 25
Barium Sulfate, Huberbrite
®
10 20 40
Post cure, 16 hours @ 232°C (450°F)
Tensile, psi 1565 2160 1265 1185 1605 1560 1885 2275 1415 1445 2035 1810
Elongation, % 225 345 285 280 290 320 275 330 255 310 305 325
Modulus 100%, psi 260 240 250 220 245 235 370 320 430 335 390 345
Hardness, Type A, pts 56 56 56 54 56 57 60 63 61 60 62 62
Air aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, % change
-41 -4 -13 -11 -20 -19 -43 -5 -21 -2 -31 -22
Elongation, % change 38 -10 13 -5 19 13 7 -14 18 -10 15 6
Hardness, Type A, pts change -6 2 -4 -1 -4 -4 -2 3 -3 -1 -3 -1
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139" O-ring 16 18 16 20 16 16 Not Run
Specic Gravity, ASTM D297
1.90 2.17 1.94 1.93 2.03 2.06 1.97 2.34 1.98 1.99 2.13 2.22
Note: MgO, Ca(OH)
2
and N990 in phr
11
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
12
Eect of Filler Level (Non-Black) continued
3M
™
Dyneon
™
Fluoroelastomer FE 5642 formulated to various durometers with various non-black llers.
70±5 Durometer 80±5 Durometer 90±5 Durometer
Compound Recipe 1 2 3 4 5 6 1 2 3 4 5 6 1 2 3 4 5 6
FE 5642 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
Ca(OH)
2
HP-XL, Hallstar
®
6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6
MgO, Elastomag
®
170 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3
Min-U-Sil
®
(5 microns) 40 62 85
Zinc Oxide, USP #1 75 100 155
NYAD
®
400 45 70 95
Calcium Carbonate, Albacar
®
5970 45 70 95
Mapico
®
Tan 10A 45 72 100
Barium Sulfate, Huberbrite
®
10 60 85 120
Post cure, 16 hours @ 232°C (450°F)
Tensile, psi 2360 2620 1735 1405 2200 1865 2280 2630 1870 1530 2465 1850 2265 2100 1920 1575 2320 1575
Elongation, % 240 305 205 280 300 350 180 300 160 220 310 300 165 215 125 150 260 225
Modulus 100%, psi 810 510 1130 615 480 450 1220 655 1465 970 860 585 1405 1075 1615 1265 1125 810
Hardness, Type A, pts 72 69 73 70 69 69 80 79 81 78 79 79 88 93 86 85 89 86
Air aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, % change -47 -20 -26 8 -32 -24 -49 -29 -29 3 -45 -17 -43 -37 -28 3 -52 -17
Elongation, % change 4 -16 15 -25 8 -9 14 -32 16 -41 -8 -3 12 -33 4 -33 -10 -9
Hardness, Type A, pts change -3 6 -2 2 0 0 1 2 -1 4 5 1 1 2 2 3 5 0
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139" O-ring 18 27 17 21 22 18 Not Run 27 53 22 25 38 27
Specic Gravity, ASTM D297
2.03 2.62 2.10 2.07 2.31 2.36 2.11 2.91 2.20 2.14 2.55 2.53 2.17 3.20 2.28 2.20 2.74 2.70
Note: MgO, Ca(OH)
2
and N990 in phr
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
13
Note: MgO, Ca(OH)
2
and N990 in phr
3M
™
Dyneon
™
Fluoroelastomer FE 5642 formulated to various durometers with various non-black llers.
Test Formulation, PHR
N990
MT
Black
NYAD
®
400
Celite
®
350
Min-U-Sil
®
5µ
Aerosil
®
R972
Mistron
®
CB
(Cyprubond)
Austin
Black
®
TiO
2
A-110
Sakai
Chemical
BaSO
4
Huberbrite
®
10
Mapico
®
Tan 10A
Albacar
®
5970 Cal
CaCO
3
Zinc
Oxide
USP #1
FE 5642 100 100 100 100 100 100 100 100 100 100 100 100
MgO, Elastomag
®
170 3 3 3 3 3 3 3 3 3 3 3 3
Ca(OH)
2
HP-XL, Hallstar
®
6 6 6 6 6 6 6 6 6 6 6 6
Filler Level 30 45 20 35 10 25 25 60 65 50 45 80
Total Parts 139 154 129 144 119 134 134 169 174 159 154 189
MDR, 6 minutes @ 177°C (350°F)
ML, in-lbs 1.4 1.5 1.6 1.5 1.1 1.3 1.6 2.0 1.8 1.6 2.3 1.9
MH, in-lbs 17.5 15.6 14.5 14.4 8.5 9.8 11.8 18.4 14.0 14.6 18.0 12.0
ts2, minutes
1.7 1.3 1.8 1.3 2.1 4.4 3.2 0.9 1.1 1.6 1.0 1.3
t'50, Minutes 2.2 1.5 2.1 1.6 2.5 6.1 5.3 1.3 1.4 2.0 1.2 1.6
t'90, Minutes 3.5 2.4 3.3 2.4 3.6 9.8 9.6 2.3 2.2 3.3 1.9 2.9
Press Cure, 10 minutes @ 177°C (350°F)
Tensile, psi 1674 1030 1742 1299 2542 2203 1198 1717 1490 2306 1722 2290
Elongation, % 420 311 436 360 602 462 621 482 438 520 416 593
Modulus 50%, psi 283 303 286 262 182 521 235 355 241 301 288 267
Modulus 100%, psi 462 470 506 432 242 980 324 486 374 511 543 393
Hardness, Type A, pts 72 70 69 69 60 73 67 78 68 70 72 71
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 2356 1845 2395 2614 3014 2504 1824 2477 2136 2756 2552 2480
Elongation, % 285 211 255 250 434 277 351 280 321 256 234 286
Modulus 50%, psi 315 365 354 344 205 621 263 502 276 352 371 339
Modulus 100%, psi 561 882 783 763 292 1235 442 745 505 720 800 571
Hardness, Type A, pts 73 72 71 71 64 73 70 85 69 74 74 74
Specic Gravity 1.8 2.1 1.9 2.0 1.9 2.0 2.1 2.3 2.3 2.4 2.0 2.6
Air Aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, % change -30 -34 -37 -45 -33 -34 -29
Too Brittle
-29 -49 -30 -12
Elongation, % change 31 15 65 46 66 51 -3 47 45 -25 37
Modulus 50, % change -20 -21 -26 -30 -8 -22 -23 -22 -6 44 3
Modulus 100%, % change -35 -35 -44 -47 -17 -33 -29 -35 -30 26 -9
Hardness, Type A, pts 1 1 -1 -1 1 1 -2 1 3 8 6
Compression Set, 70 hours @ 200ºC (392ºF), ASTM D1414
Compression Set, %,
0.139" O-ring
18 17 20 17 31 24 16 29 19 25 21 30
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
14
Low Durometer Compounds
A Type A durometer rating between 45 and 60 is considered low for uoroelastomers.
Some of the interest in low durometer uoroelastomers is a result of upgrading from silicones to
uoroelastomer. In doing this, consideration should be given to the fact that some compromises
are made in properties as the uoroelastomer durometer is reduced. These compromises include:
Lower physical properties
– In general, the lower the durometer below 55, the lower the
properties. However, the dierences are not always great.
Less compression set resistance
– The result of lower crosslink densities and process
aids/plasticizers.
Slower cures
– This can be increased using small amounts of accelerator, such as
3M
™
Dynamar
™
FC 2172 or 3M
™
Dynamar
™
FX 5166.
Higher cost
– In comparing compounds above the 45-55 durometer range, the higher level
of llers required at 55 durometer may be partially oset by diluting with lower cost raw gum.
In 45 durometer stocks, plasticizers can aid processability and also help keep costs down.
Guidelines
The following guidelines can be used to produce low durometer uoroelastomer compounds.
1.
Use high crosslink density (FE 5640Q, FC 2174, FC 2152, FE 5641Q) incorporated cure
polymers to blend 50/50 with low to medium viscosity raw gum polymers (FC 2145,
FC 2230).
2.
Use medium viscosity (FE 5640Q, FC 2174, FE 5641Q, FC 2230) polymers for compression
molding. Lower viscosities may be used for transfer or injection molding.
3.
Use 1-2 phr FC 2172 if necessary to accelerate the cure.
4.
Use 3 phr each MgO and Ca(OH)
2
.
5.
Use 1-3 phr ller.
6.
Use 0.5 to 1 phr Carnauba wax if release or tearing during molding is a problem.
Mix well or blistering may occur.
Before specifying a low
durometer compound, you
might consider one with a
higher durometer rating that
oers similar performance
characteristics. For more
information on the eect
of durometer ratings in
specic applications,
contact your 3M Technical
Representative.
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Low Durometer Compounds
Outlined below are typical compounds of this type:
A B
3M
™
Dyneon
™
FC 2174 100 50
3M
™
Dyneon
™
FC 2145 50
3M
™
Dyneon
™
FC 2172 – 1
MT Black (N990) 3 2
Ca(OH)
2
HP-XL, Hallstar
®
6 3
MgO (Maglite
®
D) 3 3
Carnauba Wax 0.5 0.5
Typical Rheological Properties
Cure ODR, 177°C (350°F)
Minimum 11.0 9.0
Time to 1 pt. Rise 4.6 4.2
Time to 30 in-lb torque 6.2 6.1
Torque at 12 minutes 77 41
Typical Physical Properties
Press Cure, 10 minutes @ 177°C (350°F)
Tensile, psi 1000 1000
Elongation, % 275 480
Modulus 100%, psi 258 163
Hardness, Type A, pts 55 47
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 1450 1300
Elongation, % 250 430
Modulus 100%, psi 265 148
Hardness, Type A, pts 55 47
Tear Strength, Die C ppi 77 91
Heat Aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, psi 1150 840
Elongation, % 255 420
Modulus 100%, psi 229 115
Hardness, Type A, pts 53 45
Compression Set, %, 0.139" O-ring, ASTM D1414
22 hours @ 200°C (392°F) 7 12
70 hours @ 200°C (392°F) 15 25
70 hours @ 149°C (300°F) 1 8
15
Note: MgO, Ca(OH)
2
and N990 in phr
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Eects of Cure Systems
Typical Properties of Vulcanized Compound.
Compound Formulations, phr
Diamine Dihydroxy Peroxide Peroxide
A B C D
3M
™
Dyneon
™
FC 2260 100 100 100 100
MT Black (N990) 30 30 30 30
MgO, Maglite
®
Y 10 – – –
MgO, Elastomag
®
170 – 3 – –
Ca(OH)
2
HP-XL, Hallstar
®
– 6 – 3
Varox
®
DBPH-50 HP – – 2.5 2.5
TAIC – – 3 3
Diamine, Diak
®
No. 3 2.5 – – –
Dihydroxy – 1.8 – –
Accelerator – 0.6 – –
ZnO – – 5.0 –
Original Properties
Mooney Scorch, 30 minutes, MS250, ASTM D1646
Minimum Viscosity, MU 90.5 66.7 48.1 53.9
t
3
, minutes 5.61 11.00 >30 >30
t
10
, minutes 7.22 16.44 >30 >30
t
18
, minutes 8.71 19.60 >30 >30
MDR, 12 minutes @ 177°C (350°F), 0.5°arc, ASTM D5289
Minimum Torque, ML, in-lb 2.7 2.8 2.2 2.3
Maximum Torque, ML, in-lb 18.0 20.7 12.6 14.6
ts2, minutes 1.8 1.3 1.0 0.9
t'50, minutes 4.4 2.2 1.6 1.6
t'90, minutes 9.2 3.9 4.0 4.6
Press Cure, 15 minutes @ 177°C (350°F)
Tensile, psi 1440 1295 1605 1790
Elongation, % 220 235 295 270
Modulus 100%, psi 660 650 450 505
Hardness, Type A, pts 71 74 69 71
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 1960 1980 2185 2230
Elongation, % 160 200 270 245
Modulus 100%, psi 915 890 570 595
Hardness, Type A, pts 75 74 72 72
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139" O-ring 53 17 34 32
Note: MgO, Ca(OH)
2
and N990 in phr
16
Cure Systems
Diamine – Added by molder
Dicinnamylidene hexane
diamine, Diak
®
No. 3
Hexamethylene diamine
carbamate, Diak
®
No. 1
Dihydroxy – Incorporated by
manufacturer in most cases
Hexauoropropylidene
diphenol (Bisphenol AF;
crosslinker)/
Triphenylbenzylphosphonium
chloride (accelerator)
Peroxide – Added by molder
2,5-dimethyl-2,5
Di(t-butyl-peroxy) hexane/
Triallyl Isocyanurate (coagent)
Each cure system
has advantages and
disadvantages.
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Processing Aids
Type Example Eect
Recommended
Loading
Waxes Carnauba Wax
Improved release, good ow/surface,
most common
0.5-2.0 phr
Plasticizers DBS/DOP Lowers viscosity, increased shrinkage 1.0-3.0 phr
Stearates Zinc Stearate, Aux 54 Improved release 0.5-3.0 phr
Polyethylene AC 1702 Improved release and ow 0.5-3.0 phr
Organosilicones WS 280 Improved release, good ow/surface 0.5-2.0 phr
Fatty Acid Esters
WB 222, HT 290 Improved release, good ow/surface 0.5-2.0 phr
Siloxane
Elastomer
3M
™
Dynamar
™
RA 5300
Improved release, good ow/surface,
minimized impact on physical properties
and shrinkage
0.5-1.0 phr
Pigments
Color Common Trade Names
Red Harwick Stan-tone
®
D-2000, D-2503 Bayferrox
®
160M
Yellow Harwick Stan-tone
®
DC-445, Bayferrox
®
1420M
Green Harwick Stan-tone
®
D-5005; Akrochem
®
414
Blue Harwick Stan-tone
®
D-4006, D-4900, Akrochem
®
626
Brown Harwick Stan-tone
®
D-8300, D-8301
Orange Harwick Stan-tone
®
D-1504, Akrochem
®
870
17
Key Considerations for Pigments
• Inorganic based pigments are preferred due to the high temperatures needed to post cure
uoroelastomers. Organic based pigments tend to degrade at high temperatures leading to
inconsistent colors and color variation.
• Use with non-black llers ZnS or ZnO, depending on ller choice the nal color will vary.
• Use ZnS, ZnO or TiO
2
for brighter, more vibrant, colors.
• Minimize use – too much negatively aects shrinkage, physical properties, and/or adhesion.
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Blending 3M
™
Dyneon
™
Incorporated Cure Gums with Raw Gum
Compound Formulations, phr A B C D E F G
FE 5640Q 100 80 60 80 60 80 60
FC 2145 – 20 40 – – – –
FC 2230 – – – 20 40 – –
FC 2178 – – – – – 20 40
MT Black (N990) 30 30 30 30 30 30 30
Ca(OH)
2
HP-XL, Hallstar
®
6 6 6 6 6 6 6
MgO, Elastomag
®
170 3 3 3 3 3 3 3
MDR, 12 minutes @ 177°C (350°F)
ML, in-lb 2.0 1.0 1.0 1.0 1.0 2.0 3.0
MH, in-lb 25.0 18.0 11.0 18.0 11.0 18.0 14.0
ts2, minutes
2.5 2.5 2.8 2.3 2.5 2.1 1.9
t'50, minutes 3.4 3.4 4.0 3.1 3.5 2.9 2.8
t'90, minutes 4.7 4.8 6.8 4.2 5.7 3.9 4.4
Press Cure, 10 minutes @ 177°C (350°F)
Tensile, psi 1425 1415 1360 1415 1420 1550 1580
Elongation, % 280 380 495 310 515 350 505
Modulus 100%, psi 610 440 305 485 300 475 355
Hardness, Type A, pts 76 72 69 72 68 71 69
Press Cure Tear Die C
Tear, ppi 117 139 145 130 145 133 148
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 2080 2180 2055 2110 2105 2160 2305
Elongation, % 215 275 350 250 340 255 330
Modulus 100%, psi 770 605 370 560 365 585 425
Hardness, Type A, pts 77 75 70 70 71 72 71
Post Cure Tear Die C
Tear, ppi 136 142 153 142 155 151 160
Heat Aging, 70 hours @ 270°C (518°F), ASTM D573
Tensile, psi 2045 1900 1770 1745 1710 2035 1820
Elongation, % 205 250 370 240 370 260 335
Modulus 100%, psi 705 510 360 470 320 515 365
Hardness, Type A, pts 77 75 70 74 72 73 71
Compression Set, 70 hours @ Room Temperature, ASTM D1414
Compression Set, %, 0.139" O-ring 9 16 33 16 31 14 26
Compression Set, 70 hours @ 200°C (392°F), ASTM D1414
Compression Set, %, 0.139" O-ring 15 18 32 17 28 16 25
Note: MgO, Ca(OH)
2
and N990 in phr
18
Blending
Fluorocarbon
Elastomers
The blending or dilution of
an incorporated cure polymer
with that of a raw gum
polymer will change certain
physical properties and
ow characteristics. The
most common reasons for
blending a raw gum polymer
with an incorporated cure
gum would be to:
• Increase elongation
• Lower modulus
• Improve tear strength
• Increase or lower
compound viscosity
(depending on which
polymers are involved)
• Adjust level of curatives
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Blending 3M
™
Dyneon
™
Peroxide Curable Fluoroelastomers
with Synthetic Elastomers
Peroxide Curable Fluorelastomers can be blended with:
• Fluorosilicones
• Silicones
• Nitriles
• Epichlorohydrin
• EPDM
Blending Fluorocarbon/Fluorosilicone Elastomers
Compound Formulations, phr
A
(80/20)
B
(60/40)
C
(60/40)
3M
™
Dyneon
™
FC 2260 80 60 60
Fluorosilicone (Dow Corning
®
LS-420) 20 40 40
Iron Oxide (Bayferrox
®
110M) – – 2.5
Silicon Dioxide (Aerosil
®
R-972) 20 20 15
Fumed Silica (Cab-O-Sil
®
HS-5) 6.5 6.5 –
Ca(OH)
2
HP-XL, Hallstar
®
3 3 –
Peroxide (Luperco 101 XL) 1.3 1.3 1.4
TAIC (Diak
®
No. 7) 1.1 1.2 1.6
Typical Rheological Properties – 12 minutes ODR @ 177°C (350°F), 100 CPM, 3° Arc
Minimum torque, in-lb 39 23 12
Time to 1 in-lb rise, minutes 3.0 2.2 2.7
Time to 80 in-lb torque, minutes 4.2 4.2 8.1
Maximum torque, 12 minutes, in-lb 95 81 53
Typical Physical Properties
Cure, 15 minutes @ 177°C (350°F)
Post Cure, 16 hours @ 200°C (392°F)
Specic Gravity 1.73 1.66 1.63
Tensile, psi 2160 1580 1390
Elongation, % 290 235 330
Modulus 100%, psi 740 660 320
Hardness, Type A, pts 83 79 63
Compression Set, 0.139' O-ring, %, ASTM D1414
70 hours @ 149°C (300°F) 28 25 18
70 hours @ 200°C (392°F) 50 50 54
Low Temperature Properties
TR
10
, °C (°F) -21 (-6) -24 (-11) -24 (-11)
Brittleness Point, °C (°F) -30 (-22) -43 (-45) -53 (-63)
Torsional Modulus, psi × 10
4
-20°C (-4°F) 1.6 0.4 0.3
-30°C (-22°F) 4.9 1.7 1.3
-40°C (-40°F) 7.6 2.7 2.1
-50°C (-58°F) 9.7 3.0 2.7
-60°C (-76°F) 11.0 4.8 3.6
Note: MgO, Ca(OH)
2
and N990 in phr
19
3M
™
Dyneon
™
Fluoroelastomer Compounding Guide
Eects of Crosslink Density on Bisphenol Cure Fluoroelastomer
Typical Properties of Vulcanized Compound
Compound Formulations, phr Low Medium High
3M
™
Dyneon
™
FC 2230 100 100 100
Bisphenol-AF 0.95 1.26 1.89
FX 5166 0.21 0.29 0.43
Ca(OH)
2
HP-XL, HallStar
®
6 6 6
MgO, Elastomag
®
170 3 3 3
MT Black (N990) 30 30 30
Total Parts 140.2 140.6 141.3
MDR, 12 minutes @ 177°C (350°F), 0.5°arc
ML, in-lb 1.2 1.2 1.2
MH, in-lb 11.0 14.9 22.9
ts2, minutes 1.4 1.2 1.2
t'50, minutes 1.9 1.5 1.5
t'90, minutes 2.9 2.2 2.1
Tand @ML 0.96 0.99 0.99
Tand @MH 0.11 0.07 0.04
Press Cure, 10 minutes @ 177°C (350°F)
Post Cure, 16 hours @ 232°C (450°F)
Tensile, psi 2046 2412 2448
Elongation, % 310 264 194
Modulus 100%, psi 447 597 911
Hardness, Type A, pts 68 71 77
Compression Set, 70 hours @ 200°C (392°F), ASTM D395 (buttons)
Compression Set, % 27 21 20
20
Increasing the crosslink density while maintaining the cure rate typically leads to the following:
• An increase in MH
• An increase in modulus @100% strain
• A decrease in elongation
• An increase in hardness
• Lower compression set
Note: MgO, Ca(OH)
2
and N990 in phr
Page is loading ...
Page is loading ...
Page is loading ...
Page is loading ...
Page is loading ...
Page is loading ...
Page is loading ...
Page is loading ...
  • Page 1 1
  • Page 2 2
  • Page 3 3
  • Page 4 4
  • Page 5 5
  • Page 6 6
  • Page 7 7
  • Page 8 8
  • Page 9 9
  • Page 10 10
  • Page 11 11
  • Page 12 12
  • Page 13 13
  • Page 14 14
  • Page 15 15
  • Page 16 16
  • Page 17 17
  • Page 18 18
  • Page 19 19
  • Page 20 20
  • Page 21 21
  • Page 22 22
  • Page 23 23
  • Page 24 24
  • Page 25 25
  • Page 26 26
  • Page 27 27
  • Page 28 28

3M Dynamar™ High Performance Rubber Additive RA 5300 User guide

Dynamar™ High Performance Rubber Additive RA 5300
3M
Brand
3M
Model
Dynamar™ High Performance Rubber Additive RA 5300
Type
User guide
Download PDF
report

Ask a question and I''ll find the answer in the document

Finding information in a document is now easier with AI

Related papers

Other documents